Zum Mechanismus der photoinduzierten Desaminierungsreaktion von Aminotriazinonherbiziden

Harun Parlar; Birgit Pletsch

doi:10.1016/0045-6535(88)90014-8

Zum Mechanismus der photoinduzierten Desaminierungsreaktion von Aminotriazinonherbiziden

Harun Parlar
, Birgit Pletsch

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6 Scopus citations

Abstract

Photokinetic experiments show that the deamination reactions of 6-tert-butyl-(or-6-Phenyl)-4 amino-3-methylthio-1,2,4-triazin-5(4H)-ons is dependent on oxygen and water. Experiments indicate further that the 6-tert-Butyl-(or-6-Phenyl-)-3-methylthio-1,2,4-triazin-5-ons were formed in an intermolecular reaction. The participation of an hydrogen transfer from the amino group to Carbonyloxygen (intramolecular) is negligible under environmental conditions.

Original language	English
Pages (from-to)	2043-2048
Number of pages	6
Journal	Chemosphere
Volume	17
Issue number	10
DOIs	https://doi.org/10.1016/0045-6535(88)90014-8
State	Published - 1988
Externally published	Yes

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title = "Zum Mechanismus der photoinduzierten Desaminierungsreaktion von Aminotriazinonherbiziden",

abstract = "Photokinetic experiments show that the deamination reactions of 6-tert-butyl-(or-6-Phenyl)-4 amino-3-methylthio-1,2,4-triazin-5(4H)-ons is dependent on oxygen and water. Experiments indicate further that the 6-tert-Butyl-(or-6-Phenyl-)-3-methylthio-1,2,4-triazin-5-ons were formed in an intermolecular reaction. The participation of an hydrogen transfer from the amino group to Carbonyloxygen (intramolecular) is negligible under environmental conditions.",

author = "Harun Parlar and Birgit Pletsch",

year = "1988",

doi = "10.1016/0045-6535(88)90014-8",

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journal = "Chemosphere",

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T1 - Zum Mechanismus der photoinduzierten Desaminierungsreaktion von Aminotriazinonherbiziden

AU - Parlar, Harun

AU - Pletsch, Birgit

PY - 1988

Y1 - 1988

N2 - Photokinetic experiments show that the deamination reactions of 6-tert-butyl-(or-6-Phenyl)-4 amino-3-methylthio-1,2,4-triazin-5(4H)-ons is dependent on oxygen and water. Experiments indicate further that the 6-tert-Butyl-(or-6-Phenyl-)-3-methylthio-1,2,4-triazin-5-ons were formed in an intermolecular reaction. The participation of an hydrogen transfer from the amino group to Carbonyloxygen (intramolecular) is negligible under environmental conditions.

AB - Photokinetic experiments show that the deamination reactions of 6-tert-butyl-(or-6-Phenyl)-4 amino-3-methylthio-1,2,4-triazin-5(4H)-ons is dependent on oxygen and water. Experiments indicate further that the 6-tert-Butyl-(or-6-Phenyl-)-3-methylthio-1,2,4-triazin-5-ons were formed in an intermolecular reaction. The participation of an hydrogen transfer from the amino group to Carbonyloxygen (intramolecular) is negligible under environmental conditions.

UR - https://www.scopus.com/pages/publications/0002061473

U2 - 10.1016/0045-6535(88)90014-8

DO - 10.1016/0045-6535(88)90014-8

M3 - Article

AN - SCOPUS:0002061473

SN - 0045-6535

VL - 17

SP - 2043

EP - 2048

JO - Chemosphere

JF - Chemosphere

IS - 10

ER -

Zum Mechanismus der photoinduzierten Desaminierungsreaktion von Aminotriazinonherbiziden

Abstract

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