Ylid-komeplexe von metallen: eikernige rhodium(I)-verbindungen

H. Schmidbaur; G. Blaschke; H. J. Füller; H. P. Scherm

doi:10.1016/S0022-328X(00)91196-3

Ylid-komeplexe von metallen: eikernige rhodium(I)-verbindungen

H. Schmidbaur, G. Blaschke, H. J. Füller, H. P. Scherm

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Treatment of the phosphorus ylides [(CH₃)₃C]₂P(CH₃)CH₂ and (CH₂)₅P(CH₃CH₂ with [(1,5-C₈H₁₂)RhCl]₂ (I) gives the mononuclear organometallic compounds (C₈H₁₂)Rh(CH₂)₂P[C(CH₃)₃]₂ (II) and (C₈H₁₂Rh(CH₂)₂P(CH₂)₅. The olefinic ligand in II can be substituted by CO and P(CH₃)₃ with formation of the corresponding bis(carbonyl) and bis(trimethylphosphine) complexes, respectively. With methylphospholanium methylide an insoluble yellow material is obtained, which is probably a polymeric species. The double ylide (CH₃)₃PNP(CH₃)₂CH₂ and I give a particularly stable chelate ylide complex (C₈H₁₂)Rh[CH₂P(CH₃)₂]₂N. The reaction syntheses follow the trasylidation scheme with precipitation of equimolar amounts of phosphonium salts as by-products.

Original language	German
Pages (from-to)	41-46
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	160
Issue number	1
DOIs	https://doi.org/10.1016/S0022-328X(00)91196-3
State	Published - 31 Oct 1978
Externally published	Yes

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title = "Ylid-komeplexe von metallen: eikernige rhodium(I)-verbindungen",

abstract = "Treatment of the phosphorus ylides [(CH3)3C]2P(CH3)CH2 and (CH2)5P(CH3CH2 with [(1,5-C8H12)RhCl]2 (I) gives the mononuclear organometallic compounds (C8H12)Rh(CH2)2P[C(CH3)3]2 (II) and (C8H12Rh(CH2)2P(CH2)5. The olefinic ligand in II can be substituted by CO and P(CH3)3 with formation of the corresponding bis(carbonyl) and bis(trimethylphosphine) complexes, respectively. With methylphospholanium methylide an insoluble yellow material is obtained, which is probably a polymeric species. The double ylide (CH3)3PNP(CH3)2CH2 and I give a particularly stable chelate ylide complex (C8H12)Rh[CH2P(CH3)2]2N. The reaction syntheses follow the trasylidation scheme with precipitation of equimolar amounts of phosphonium salts as by-products.",

author = "H. Schmidbaur and G. Blaschke and F{\"u}ller, {H. J.} and Scherm, {H. P.}",

year = "1978",

month = oct,

day = "31",

doi = "10.1016/S0022-328X(00)91196-3",

language = "Deutsch",

volume = "160",

pages = "41--46",

journal = "Journal of Organometallic Chemistry",

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T1 - Ylid-komeplexe von metallen

T2 - eikernige rhodium(I)-verbindungen

AU - Schmidbaur, H.

AU - Blaschke, G.

AU - Füller, H. J.

AU - Scherm, H. P.

PY - 1978/10/31

Y1 - 1978/10/31

N2 - Treatment of the phosphorus ylides [(CH3)3C]2P(CH3)CH2 and (CH2)5P(CH3CH2 with [(1,5-C8H12)RhCl]2 (I) gives the mononuclear organometallic compounds (C8H12)Rh(CH2)2P[C(CH3)3]2 (II) and (C8H12Rh(CH2)2P(CH2)5. The olefinic ligand in II can be substituted by CO and P(CH3)3 with formation of the corresponding bis(carbonyl) and bis(trimethylphosphine) complexes, respectively. With methylphospholanium methylide an insoluble yellow material is obtained, which is probably a polymeric species. The double ylide (CH3)3PNP(CH3)2CH2 and I give a particularly stable chelate ylide complex (C8H12)Rh[CH2P(CH3)2]2N. The reaction syntheses follow the trasylidation scheme with precipitation of equimolar amounts of phosphonium salts as by-products.

AB - Treatment of the phosphorus ylides [(CH3)3C]2P(CH3)CH2 and (CH2)5P(CH3CH2 with [(1,5-C8H12)RhCl]2 (I) gives the mononuclear organometallic compounds (C8H12)Rh(CH2)2P[C(CH3)3]2 (II) and (C8H12Rh(CH2)2P(CH2)5. The olefinic ligand in II can be substituted by CO and P(CH3)3 with formation of the corresponding bis(carbonyl) and bis(trimethylphosphine) complexes, respectively. With methylphospholanium methylide an insoluble yellow material is obtained, which is probably a polymeric species. The double ylide (CH3)3PNP(CH3)2CH2 and I give a particularly stable chelate ylide complex (C8H12)Rh[CH2P(CH3)2]2N. The reaction syntheses follow the trasylidation scheme with precipitation of equimolar amounts of phosphonium salts as by-products.

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U2 - 10.1016/S0022-328X(00)91196-3

DO - 10.1016/S0022-328X(00)91196-3

M3 - Artikel

AN - SCOPUS:0343498012

SN - 0022-328X

VL - 160

SP - 41

EP - 46

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

Ylid-komeplexe von metallen: eikernige rhodium(I)-verbindungen

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