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X-ray photoelectron spectra of La0.7Ca0.3MnO3 and La0.7Ca0.3Mn0.97Cu0.03O3 perovskite oxides

  • Astrid Krmpotić
  • , Dirk H. Busch
  • , Ivan Bubić
  • , Friedemann Gebhardt
  • , Hartmut Hengel
  • , Milena Hasan
  • , Anthony A. Scalzo
  • , Ulrich H. Koszinowski
  • , Stipan Jonjiić
  • Faculty of Medicine, University of Rijeka
  • Technical University of Munich
  • Robert Koch Institut
  • University of Western Australia
  • University of Munich

Research output: Contribution to journalArticlepeer-review

11 Scopus citations

Abstract

X-ray photoelectron spectroscopy was used to identify the oxidation states of cations in La0.7Ca0.3MnO3 and La 0.7Ca0.3Mn0.97Cu0.03O3 perovskite oxides, to determine the surface composition of the samples, and to assess the effect of the Cu dopant on the electronic spectrum of the material. The binding energies of the La 4d, Ca 2p, Mn 2p, and O 1s core levels were determined, and the effect of the Cu dopant on the shape of the La 4d and O 1s peaks was analyzed.

Original languageEnglish
Pages (from-to)261-264
Number of pages4
JournalInorganic Materials
Volume38
Issue number3
DOIs
StatePublished - Mar 2002

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