X-Ray and Neutron Grazing Incidence Scattering Study of a Ternary Ultra-thin Polymer Blend Film

J. S. Gutmann; P. Müller-Buschbaum; M. Wolkenhauer; N. Hermsdorf; M. Stamm

doi:10.1081/MB-120027759

X-Ray and Neutron Grazing Incidence Scattering Study of a Ternary Ultra-thin Polymer Blend Film

J. S. Gutmann, P. Müller-Buschbaum, M. Wolkenhauer, N. Hermsdorf, M. Stamm

Chair of Functional Materials

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Structure formation in a multicomponent ultrathin polymer blend film was investigated at and below the surface with grazing incidence X-ray and neutron scattering and scanning force microscopy (SFM). Two films were examined. First a strongly incompatible binary polymer blend film in which a buried structure was clearly identified. This binary blend film then was compared with a ternary blend film into which 5 wt% of a compatibilizing copolymer had been added. The addition of the compatibilizer was found to decrease the size of the internal structures, while leaving the surface morphology unchanged.

Original language	English
Pages (from-to)	207-217
Number of pages	11
Journal	Journal of Macromolecular Science - Physics
Volume	43 B
Issue number	1
DOIs	https://doi.org/10.1081/MB-120027759
State	Published - Jan 2004

Keywords

Grazing incidence scattering
Multicomponent systems
Polymers
Ultrathin films

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10.1081/MB-120027759

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title = "X-Ray and Neutron Grazing Incidence Scattering Study of a Ternary Ultra-thin Polymer Blend Film",

abstract = "Structure formation in a multicomponent ultrathin polymer blend film was investigated at and below the surface with grazing incidence X-ray and neutron scattering and scanning force microscopy (SFM). Two films were examined. First a strongly incompatible binary polymer blend film in which a buried structure was clearly identified. This binary blend film then was compared with a ternary blend film into which 5 wt\% of a compatibilizing copolymer had been added. The addition of the compatibilizer was found to decrease the size of the internal structures, while leaving the surface morphology unchanged.",

keywords = "Grazing incidence scattering, Multicomponent systems, Polymers, Ultrathin films",

author = "Gutmann, \{J. S.\} and P. M{\"u}ller-Buschbaum and M. Wolkenhauer and N. Hermsdorf and M. Stamm",

note = "Funding Information: The authors would like to acknowledge the help of R. Cubit at the D22 beamline of the ILL, France, as well as the help of S. Cunis and G. v. Krosigk at the BW4 beamline of the Hasylab, and R. Gehrke for his general support at the Hasylab. Financial support within the framework of the GKSS project V6.1.01.G.01-HS3 and the DFG Schwerpunktprogramm “Benetzung und Strukturbildung” (STA 314-8) is also acknowledged.",

year = "2004",

month = jan,

doi = "10.1081/MB-120027759",

language = "English",

volume = "43 B",

pages = "207--217",

journal = "Journal of Macromolecular Science - Physics",

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AU - Gutmann, J. S.

AU - Müller-Buschbaum, P.

AU - Wolkenhauer, M.

AU - Hermsdorf, N.

AU - Stamm, M.

N1 - Funding Information: The authors would like to acknowledge the help of R. Cubit at the D22 beamline of the ILL, France, as well as the help of S. Cunis and G. v. Krosigk at the BW4 beamline of the Hasylab, and R. Gehrke for his general support at the Hasylab. Financial support within the framework of the GKSS project V6.1.01.G.01-HS3 and the DFG Schwerpunktprogramm “Benetzung und Strukturbildung” (STA 314-8) is also acknowledged.

PY - 2004/1

Y1 - 2004/1

N2 - Structure formation in a multicomponent ultrathin polymer blend film was investigated at and below the surface with grazing incidence X-ray and neutron scattering and scanning force microscopy (SFM). Two films were examined. First a strongly incompatible binary polymer blend film in which a buried structure was clearly identified. This binary blend film then was compared with a ternary blend film into which 5 wt% of a compatibilizing copolymer had been added. The addition of the compatibilizer was found to decrease the size of the internal structures, while leaving the surface morphology unchanged.

AB - Structure formation in a multicomponent ultrathin polymer blend film was investigated at and below the surface with grazing incidence X-ray and neutron scattering and scanning force microscopy (SFM). Two films were examined. First a strongly incompatible binary polymer blend film in which a buried structure was clearly identified. This binary blend film then was compared with a ternary blend film into which 5 wt% of a compatibilizing copolymer had been added. The addition of the compatibilizer was found to decrease the size of the internal structures, while leaving the surface morphology unchanged.

KW - Grazing incidence scattering

KW - Multicomponent systems

KW - Polymers

KW - Ultrathin films

UR - https://www.scopus.com/pages/publications/1642283556

U2 - 10.1081/MB-120027759

DO - 10.1081/MB-120027759

M3 - Article

AN - SCOPUS:1642283556

SN - 0022-2348

VL - 43 B

SP - 207

EP - 217

JO - Journal of Macromolecular Science - Physics

JF - Journal of Macromolecular Science - Physics

IS - 1

ER -

X-Ray and Neutron Grazing Incidence Scattering Study of a Ternary Ultra-thin Polymer Blend Film

Abstract

Keywords

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