Wood-water interactions of primers to enhance wood-polyurethane bonding performance

Today, using one-component polyurethane (1c-PUR) adhesives in the manufacturing of engineered wood products from spruce is common practice. However, the use of other wood species can require the application of a primer to fulfill normative requirements. Previous research shows the primers’ effectiveness, especially in moist environments. However, the primers’ exact mode of action remains not yet fully understood. We hypothesize a reduction in the hygroscopic behavior of the primer-treated wood—intensity and kinetics—that could reduce the formation of stresses in the bond line region. To test this hypothesis, two commercially available primers, based on Polysorbate 20 and poly(ethylene glycol), and the hydroxymethylated resorcinol (HMR) primer are examined with wood from beech, birch, larch, and Douglas fir. Swelling experiments show that of each primer a portion infiltrates and swells the wood cell walls, affecting the wood’s hygroscopic and mechanical properties. In stepwise sorption experiments, it is seen that the primers influence differently the amount of moisture uptaken by the wood (adsorption). The rate at which the moisture spreads within the wood (diffusivity) also changed differently for the primers, while the rate at which the moisture moves through the wood (permeability) remains unchanged. The application of all primers improves the bulk flow behavior and thus the void penetration of the adhesive into the lumina in the interphase region, which in turn leads to a reduced bond line thickness. All three primers improve the tensile shear strength. The hygroscopic changes caused by the primers appear too small to be claimed as the sole and primary cause of their functionality, whereas more relevance is seen in the primers’ cell wall infiltration and the increased adhesive’s void penetration.