Where does the energy go for radiationless transitions? The 3B1u {rightwards squiggle arrow} 1A1g transition for benzene and deuterobenzene

S. Fischer; S. Schneider

doi:10.1016/0009-2614(71)80317-2

Where does the energy go for radiationless transitions? The ³B_1u {rightwards squiggle arrow} ¹A_1g transition for benzene and deuterobenzene

S. Fischer
, S. Schneider

Northwestern University

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

Starting from a previously derived correlation function expression the rate for intersystem crossing has been evaluated. It is found that only 66% (55%) of the energy goes into the CH (CD) breathing mode. The other major energy sinks involve the totally symmetric skeletal breathing mode (990 cm^-1), the e_2g stretching mode (1584 cm^-1) and, to a smaller extent, the out-of-plane vibrations.

Original language	English
Pages (from-to)	392-396
Number of pages	5
Journal	Chemical Physics Letters
Volume	10
Issue number	4
DOIs	https://doi.org/10.1016/0009-2614(71)80317-2
State	Published - 15 Aug 1971
Externally published	Yes

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title = "Where does the energy go for radiationless transitions? The 3B1u \{rightwards squiggle arrow\} 1A1g transition for benzene and deuterobenzene",

abstract = "Starting from a previously derived correlation function expression the rate for intersystem crossing has been evaluated. It is found that only 66\% (55\%) of the energy goes into the CH (CD) breathing mode. The other major energy sinks involve the totally symmetric skeletal breathing mode (990 cm-1), the e2g stretching mode (1584 cm-1) and, to a smaller extent, the out-of-plane vibrations.",

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AU - Schneider, S.

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Y1 - 1971/8/15

N2 - Starting from a previously derived correlation function expression the rate for intersystem crossing has been evaluated. It is found that only 66% (55%) of the energy goes into the CH (CD) breathing mode. The other major energy sinks involve the totally symmetric skeletal breathing mode (990 cm-1), the e2g stretching mode (1584 cm-1) and, to a smaller extent, the out-of-plane vibrations.

AB - Starting from a previously derived correlation function expression the rate for intersystem crossing has been evaluated. It is found that only 66% (55%) of the energy goes into the CH (CD) breathing mode. The other major energy sinks involve the totally symmetric skeletal breathing mode (990 cm-1), the e2g stretching mode (1584 cm-1) and, to a smaller extent, the out-of-plane vibrations.

UR - https://www.scopus.com/pages/publications/33645515107

U2 - 10.1016/0009-2614(71)80317-2

DO - 10.1016/0009-2614(71)80317-2

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AN - SCOPUS:33645515107

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JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 4

ER -

Where does the energy go for radiationless transitions? The ³B_1u {rightwards squiggle arrow} ¹A_1g transition for benzene and deuterobenzene

Abstract

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