Weak Intramolecular Bonding Relationships: The Conformation‐Determining Attractive Interaction between Gold(I) Centers

Hubert Schmidbaur, Wilhelm Graf, Gerhard Müller

Research output: Contribution to journalArticlepeer-review

311 Scopus citations

Abstract

AuAu distances of only 3.000 Å in the complex 2 are convincing evidence for the existence of attractive interactions between Au1 centers. 2 is formed from 1 and [(CO)AuCl] with rotation of a CP bond. 1, Ph instead of Me, is sterically too strongly hindered for this reaction. (Figure Presented.)

Original languageEnglish
Pages (from-to)417-419
Number of pages3
JournalAngewandte Chemie International Edition in English
Volume27
Issue number3
DOIs
StatePublished - Mar 1988
Externally publishedYes

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