TY - JOUR
T1 - Water-soluble metal complexes and catalysts. Part XI. Novel ligands from tris(hydroxymethyl)phosphane and amino acids
T2 - Synthesis and catalytic studies in two-phase hydroformylation
AU - Baskakov, Denys
AU - Herrmann, Wolfgang A.
PY - 2008/3/18
Y1 - 2008/3/18
N2 - Novel water-soluble ligands were prepared in high yields by condensation of various amino acids with tris(hydroxymethyl)phosphane. Rhodium complexes of these ligands, formed in situ, were tested in two-phase hydroformylation of propylene. Selectivity observed with these ligand systems is easily controlled by altering the pH of the reaction mixture.
AB - Novel water-soluble ligands were prepared in high yields by condensation of various amino acids with tris(hydroxymethyl)phosphane. Rhodium complexes of these ligands, formed in situ, were tested in two-phase hydroformylation of propylene. Selectivity observed with these ligand systems is easily controlled by altering the pH of the reaction mixture.
KW - Amino acids
KW - Rhodium catalysts
KW - Two-phase hydroformylation
UR - http://www.scopus.com/inward/record.url?scp=40049102342&partnerID=8YFLogxK
U2 - 10.1016/j.molcata.2007.12.006
DO - 10.1016/j.molcata.2007.12.006
M3 - Article
AN - SCOPUS:40049102342
SN - 1381-1169
VL - 283
SP - 166
EP - 170
JO - Journal of Molecular Catalysis A: Chemical
JF - Journal of Molecular Catalysis A: Chemical
IS - 1-2
ER -