Water-soluble carbene complexes as catalysts for the hydrogenation of acetophenone under hydrogen pressure

Hitrisia Syska; Wolfgang A. Herrmann; Fritz E. Kühn

doi:10.1016/j.jorganchem.2012.01.001

Water-soluble carbene complexes as catalysts for the hydrogenation of acetophenone under hydrogen pressure

Technical University of Munich

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40 Scopus citations

Abstract

The synthesis of water-soluble Rh(I), Ir(I), and Ru(II) N-heterocyclic carbene complexes is described. These complexes are applied as catalysts for aqueous phase hydrogenation reactions. Good hydrogenation activities under ca. 40 atm pressure H ₂ at room temperature are observed.

Original language	English
Pages (from-to)	56-62
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	703
DOIs	https://doi.org/10.1016/j.jorganchem.2012.01.001
State	Published - 15 Apr 2012

Keywords

Acetophenone
Aqueous hydrogenation
Homogeneous catalysis
Water-soluble N-heterocyclic carbenes

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10.1016/j.jorganchem.2012.01.001

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title = "Water-soluble carbene complexes as catalysts for the hydrogenation of acetophenone under hydrogen pressure",

abstract = "The synthesis of water-soluble Rh(I), Ir(I), and Ru(II) N-heterocyclic carbene complexes is described. These complexes are applied as catalysts for aqueous phase hydrogenation reactions. Good hydrogenation activities under ca. 40 atm pressure H 2 at room temperature are observed.",

keywords = "Acetophenone, Aqueous hydrogenation, Homogeneous catalysis, Water-soluble N-heterocyclic carbenes",

author = "Hitrisia Syska and Herrmann, \{Wolfgang A.\} and K{\"u}hn, \{Fritz E.\}",

year = "2012",

month = apr,

day = "15",

doi = "10.1016/j.jorganchem.2012.01.001",

language = "English",

volume = "703",

pages = "56--62",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

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T1 - Water-soluble carbene complexes as catalysts for the hydrogenation of acetophenone under hydrogen pressure

AU - Syska, Hitrisia

AU - Herrmann, Wolfgang A.

AU - Kühn, Fritz E.

PY - 2012/4/15

Y1 - 2012/4/15

N2 - The synthesis of water-soluble Rh(I), Ir(I), and Ru(II) N-heterocyclic carbene complexes is described. These complexes are applied as catalysts for aqueous phase hydrogenation reactions. Good hydrogenation activities under ca. 40 atm pressure H 2 at room temperature are observed.

AB - The synthesis of water-soluble Rh(I), Ir(I), and Ru(II) N-heterocyclic carbene complexes is described. These complexes are applied as catalysts for aqueous phase hydrogenation reactions. Good hydrogenation activities under ca. 40 atm pressure H 2 at room temperature are observed.

KW - Acetophenone

KW - Aqueous hydrogenation

KW - Homogeneous catalysis

KW - Water-soluble N-heterocyclic carbenes

UR - https://www.scopus.com/pages/publications/84857063715

U2 - 10.1016/j.jorganchem.2012.01.001

DO - 10.1016/j.jorganchem.2012.01.001

M3 - Article

AN - SCOPUS:84857063715

SN - 0022-328X

VL - 703

SP - 56

EP - 62

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -

Water-soluble carbene complexes as catalysts for the hydrogenation of acetophenone under hydrogen pressure

Abstract

Keywords

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