Vibronic coupling in the pE″ Rydberg series of NH3

A. Staib; W. Domcke

doi:10.1016/0009-2614(93)89194-M

Vibronic coupling in the pE″ Rydberg series of NH₃

A. Staib
, W. Domcke

TUM Emeriti of Excellence

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

The Jahn-Teller effect in the pE″ Rydberg series on NH₃ is investigated within a simple multi-channel-quantum-defect-type model. The parameters of the model are determined from recently observed infrared-optical double resonance spectra of the B̃¹E″ (3p_x,y band system. Jahn-Teller induced vibrational autoionization effects and pronounced perturbations of high Rydberg members are analyzed. a.

Original language	English
Pages (from-to)	505-510
Number of pages	6
Journal	Chemical Physics Letters
Volume	204
Issue number	5-6
DOIs	https://doi.org/10.1016/0009-2614(93)89194-M
State	Published - 26 Mar 1993

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title = "Vibronic coupling in the pE″ Rydberg series of NH3",

abstract = "The Jahn-Teller effect in the pE″ Rydberg series on NH3 is investigated within a simple multi-channel-quantum-defect-type model. The parameters of the model are determined from recently observed infrared-optical double resonance spectra of the {\~B}1E″ (3px,y band system. Jahn-Teller induced vibrational autoionization effects and pronounced perturbations of high Rydberg members are analyzed. a.",

author = "A. Staib and W. Domcke",

note = "Funding Information: This work has been supported by the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie.",

year = "1993",

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doi = "10.1016/0009-2614(93)89194-M",

language = "English",

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journal = "Chemical Physics Letters",

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T1 - Vibronic coupling in the pE″ Rydberg series of NH3

AU - Staib, A.

AU - Domcke, W.

N1 - Funding Information: This work has been supported by the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie.

PY - 1993/3/26

Y1 - 1993/3/26

N2 - The Jahn-Teller effect in the pE″ Rydberg series on NH3 is investigated within a simple multi-channel-quantum-defect-type model. The parameters of the model are determined from recently observed infrared-optical double resonance spectra of the B̃1E″ (3px,y band system. Jahn-Teller induced vibrational autoionization effects and pronounced perturbations of high Rydberg members are analyzed. a.

AB - The Jahn-Teller effect in the pE″ Rydberg series on NH3 is investigated within a simple multi-channel-quantum-defect-type model. The parameters of the model are determined from recently observed infrared-optical double resonance spectra of the B̃1E″ (3px,y band system. Jahn-Teller induced vibrational autoionization effects and pronounced perturbations of high Rydberg members are analyzed. a.

UR - https://www.scopus.com/pages/publications/0347909874

U2 - 10.1016/0009-2614(93)89194-M

DO - 10.1016/0009-2614(93)89194-M

M3 - Article

AN - SCOPUS:0347909874

SN - 0009-2614

VL - 204

SP - 505

EP - 510

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 5-6

ER -

Vibronic coupling in the pE″ Rydberg series of NH₃

Abstract

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