Vibrational study on rhenium oxo complexes: Normal coordinate analysis of H3C-ReO3 and [L-ReO3]+ {L = Ph3P=C=PPh3}

R. Pikl; K. Weber; J. Sundermeyer; W. A. Herrmann; W. Kiefer

doi:10.1016/s0924-2031(97)00006-4

Vibrational study on rhenium oxo complexes: Normal coordinate analysis of H₃C-ReO₃ and [L-ReO₃]⁺ {L = Ph₃P=C=PPh₃}

R. Pikl, K. Weber, J. Sundermeyer, W. A. Herrmann, W. Kiefer

Technical University of Munich

University of Würzburg

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Vibrational studies of the catalyst H₃C-ReO₃ 1 and [L-ReO₃]⁺ {L = Ph₃P=C=PPh₃} 2 were performed by means of infrared and polarized Raman spectroscopy. A normal coordinate analysis of H₃C-ReO₃ and [L-ReO⁺₃] with the ligand as point mass was carried out and assignments were made for the modes observed. The difference between the two metal centers is discussed on the basis of the force field. Furthermore the potential energy distribution for the various modes has been calculated.

Original language	English
Pages (from-to)	299-302
Number of pages	4
Journal	Vibrational Spectroscopy
Volume	14
Issue number	2
DOIs	https://doi.org/10.1016/s0924-2031(97)00006-4
State	Published - May 1997

Keywords

Bistriphenylphosphoniomethylidentrioxorhenium
Methyltrioxorhenium
Normal coordinate analysis
Potential energy distribution
Raman spectroscopy
Rhenium oxides
Vibrational analysis

Access to Document

10.1016/s0924-2031(97)00006-4

Cite this

@article{09e88587f22d4c0b9891ec99e0773c00,

title = "Vibrational study on rhenium oxo complexes: Normal coordinate analysis of H3C-ReO3 and [L-ReO3]+ {L = Ph3P=C=PPh3}",

abstract = "Vibrational studies of the catalyst H3C-ReO3 1 and [L-ReO3]+ {L = Ph3P=C=PPh3} 2 were performed by means of infrared and polarized Raman spectroscopy. A normal coordinate analysis of H3C-ReO3 and [L-ReO+3] with the ligand as point mass was carried out and assignments were made for the modes observed. The difference between the two metal centers is discussed on the basis of the force field. Furthermore the potential energy distribution for the various modes has been calculated.",

keywords = "Bistriphenylphosphoniomethylidentrioxorhenium, Methyltrioxorhenium, Normal coordinate analysis, Potential energy distribution, Raman spectroscopy, Rhenium oxides, Vibrational analysis",

author = "R. Pikl and K. Weber and J. Sundermeyer and Herrmann, {W. A.} and W. Kiefer",

year = "1997",

month = may,

doi = "10.1016/s0924-2031(97)00006-4",

language = "English",

volume = "14",

pages = "299--302",

journal = "Vibrational Spectroscopy",

issn = "0924-2031",

publisher = "Elsevier B.V.",

number = "2",

}

TY - JOUR

T1 - Vibrational study on rhenium oxo complexes

T2 - Normal coordinate analysis of H3C-ReO3 and [L-ReO3]+ {L = Ph3P=C=PPh3}

AU - Pikl, R.

AU - Weber, K.

AU - Sundermeyer, J.

AU - Herrmann, W. A.

AU - Kiefer, W.

PY - 1997/5

Y1 - 1997/5

N2 - Vibrational studies of the catalyst H3C-ReO3 1 and [L-ReO3]+ {L = Ph3P=C=PPh3} 2 were performed by means of infrared and polarized Raman spectroscopy. A normal coordinate analysis of H3C-ReO3 and [L-ReO+3] with the ligand as point mass was carried out and assignments were made for the modes observed. The difference between the two metal centers is discussed on the basis of the force field. Furthermore the potential energy distribution for the various modes has been calculated.

AB - Vibrational studies of the catalyst H3C-ReO3 1 and [L-ReO3]+ {L = Ph3P=C=PPh3} 2 were performed by means of infrared and polarized Raman spectroscopy. A normal coordinate analysis of H3C-ReO3 and [L-ReO+3] with the ligand as point mass was carried out and assignments were made for the modes observed. The difference between the two metal centers is discussed on the basis of the force field. Furthermore the potential energy distribution for the various modes has been calculated.

KW - Bistriphenylphosphoniomethylidentrioxorhenium

KW - Methyltrioxorhenium

KW - Normal coordinate analysis

KW - Potential energy distribution

KW - Raman spectroscopy

KW - Rhenium oxides

KW - Vibrational analysis

UR - http://www.scopus.com/inward/record.url?scp=0043130138&partnerID=8YFLogxK

U2 - 10.1016/s0924-2031(97)00006-4

DO - 10.1016/s0924-2031(97)00006-4

M3 - Article

AN - SCOPUS:0043130138

SN - 0924-2031

VL - 14

SP - 299

EP - 302

JO - Vibrational Spectroscopy

JF - Vibrational Spectroscopy

IS - 2

ER -

Vibrational study on rhenium oxo complexes: Normal coordinate analysis of H₃C-ReO₃ and [L-ReO₃]⁺ {L = Ph₃P=C=PPh₃}

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this