Vibrational state dependence of the photoelectron angular asymmetry parameter caused by vibronic coupling

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Abstract

It is shown that the dependence of the angular asymmetry parameter β on the vibrational state, which has been found in the photoelectron spectra of some polyatomic molecules, can be explained by vibronic interactions. It is proposed that measurements of β as a function of the vibrational state may be used as a tool to analyze vibronic coupling effects in photoelectron spectra.

Original languageEnglish
Pages (from-to)11-15
Number of pages5
JournalPhysica Scripta
Volume19
Issue number1
DOIs
StatePublished - 1 Jan 1979
Externally publishedYes

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