Vibrational spectroscopy of matrix-isolated, mass-selected cyanoacetylene cations

A. M. Smith-Gicklhorn; M. Lorenz; R. Kołos; V. E. Bondybey

doi:10.1063/1.1405019

Vibrational spectroscopy of matrix-isolated, mass-selected cyanoacetylene cations

A. M. Smith-Gicklhorn
, M. Lorenz
, R. Kołos
, V. E. Bondybey

Chair of Physical Chemistry

Technical University of Munich
Institute of Physical Chemistry of the Polish Academy of Sciences

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

Vibrational spectroscopy of matrix-isolated, mass-selected cyanoacetylene cations in neon matrices was investigated using infrared spectroscopy. The matrices containing the HC₃N⁺ cation and its deuterated analogue were generated using mass-selective ion deposition. It is found that in spite of spraying of the sample by electrons simultaneously with the ion deposition, the degree of ion-electron recombination occuring in the cold 7 K matrix is relatively small.

Original language	English
Pages (from-to)	7534-7542
Number of pages	9
Journal	Journal of Chemical Physics
Volume	115
Issue number	16
DOIs	https://doi.org/10.1063/1.1405019
State	Published - 22 Oct 2001

Access to Document

10.1063/1.1405019

Cite this

@article{4cdb1e00c63341fba7616d6c8889cc1b,

title = "Vibrational spectroscopy of matrix-isolated, mass-selected cyanoacetylene cations",

abstract = "Vibrational spectroscopy of matrix-isolated, mass-selected cyanoacetylene cations in neon matrices was investigated using infrared spectroscopy. The matrices containing the HC3N+ cation and its deuterated analogue were generated using mass-selective ion deposition. It is found that in spite of spraying of the sample by electrons simultaneously with the ion deposition, the degree of ion-electron recombination occuring in the cold 7 K matrix is relatively small.",

author = "Smith-Gicklhorn, \{A. M.\} and M. Lorenz and R. Ko{\l}os and Bondybey, \{V. E.\}",

year = "2001",

month = oct,

day = "22",

doi = "10.1063/1.1405019",

language = "English",

volume = "115",

pages = "7534--7542",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "16",

}

TY - JOUR

T1 - Vibrational spectroscopy of matrix-isolated, mass-selected cyanoacetylene cations

AU - Smith-Gicklhorn, A. M.

AU - Lorenz, M.

AU - Kołos, R.

AU - Bondybey, V. E.

PY - 2001/10/22

Y1 - 2001/10/22

N2 - Vibrational spectroscopy of matrix-isolated, mass-selected cyanoacetylene cations in neon matrices was investigated using infrared spectroscopy. The matrices containing the HC3N+ cation and its deuterated analogue were generated using mass-selective ion deposition. It is found that in spite of spraying of the sample by electrons simultaneously with the ion deposition, the degree of ion-electron recombination occuring in the cold 7 K matrix is relatively small.

AB - Vibrational spectroscopy of matrix-isolated, mass-selected cyanoacetylene cations in neon matrices was investigated using infrared spectroscopy. The matrices containing the HC3N+ cation and its deuterated analogue were generated using mass-selective ion deposition. It is found that in spite of spraying of the sample by electrons simultaneously with the ion deposition, the degree of ion-electron recombination occuring in the cold 7 K matrix is relatively small.

UR - https://www.scopus.com/pages/publications/0035935360

U2 - 10.1063/1.1405019

DO - 10.1063/1.1405019

M3 - Article

AN - SCOPUS:0035935360

SN - 0021-9606

VL - 115

SP - 7534

EP - 7542

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 16

ER -

Vibrational spectroscopy of matrix-isolated, mass-selected cyanoacetylene cations

Abstract

Access to Document

Other files and links

Fingerprint

Cite this