Vibrational spectroscopy of matrix-isolated, mass-selected cyanoacetylene cations

A. M. Smith-Gicklhorn; M. Lorenz; R. Kołos; V. E. Bondybey

doi:10.1063/1.1405019

Vibrational spectroscopy of matrix-isolated, mass-selected cyanoacetylene cations

A. M. Smith-Gicklhorn, M. Lorenz, R. Kołos, V. E. Bondybey

Chair of Physical Chemistry

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Abstract

Vibrational spectroscopy of matrix-isolated, mass-selected cyanoacetylene cations in neon matrices was investigated using infrared spectroscopy. The matrices containing the HC₃N⁺ cation and its deuterated analogue were generated using mass-selective ion deposition. It is found that in spite of spraying of the sample by electrons simultaneously with the ion deposition, the degree of ion-electron recombination occuring in the cold 7 K matrix is relatively small.

Original language	English
Pages (from-to)	7534-7542
Number of pages	9
Journal	Journal of Chemical Physics
Volume	115
Issue number	16
DOIs	https://doi.org/10.1063/1.1405019
State	Published - 22 Oct 2001

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abstract = "Vibrational spectroscopy of matrix-isolated, mass-selected cyanoacetylene cations in neon matrices was investigated using infrared spectroscopy. The matrices containing the HC3N+ cation and its deuterated analogue were generated using mass-selective ion deposition. It is found that in spite of spraying of the sample by electrons simultaneously with the ion deposition, the degree of ion-electron recombination occuring in the cold 7 K matrix is relatively small.",

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AU - Lorenz, M.

AU - Kołos, R.

AU - Bondybey, V. E.

PY - 2001/10/22

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N2 - Vibrational spectroscopy of matrix-isolated, mass-selected cyanoacetylene cations in neon matrices was investigated using infrared spectroscopy. The matrices containing the HC3N+ cation and its deuterated analogue were generated using mass-selective ion deposition. It is found that in spite of spraying of the sample by electrons simultaneously with the ion deposition, the degree of ion-electron recombination occuring in the cold 7 K matrix is relatively small.

AB - Vibrational spectroscopy of matrix-isolated, mass-selected cyanoacetylene cations in neon matrices was investigated using infrared spectroscopy. The matrices containing the HC3N+ cation and its deuterated analogue were generated using mass-selective ion deposition. It is found that in spite of spraying of the sample by electrons simultaneously with the ion deposition, the degree of ion-electron recombination occuring in the cold 7 K matrix is relatively small.

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Vibrational spectroscopy of matrix-isolated, mass-selected cyanoacetylene cations

Abstract

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