Abstract
Several higher lying excited electronic states of TlRg (Rg = Ar, Kr, Xe) van der Waals complexes have been investigated. Analysis of the transitions arising from the 6d 2D ↔ 6p 2P transition of Tl atoms provides information about their ground state binding energies, and leads to the conclusion that the potentials of the lowest excited B 2Σ+ states of the complexes exhibit a substantial (100-150 cm-) potential barrier.
Original language | English |
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Pages (from-to) | 227-235 |
Number of pages | 9 |
Journal | Chemical Physics |
Volume | 201 |
Issue number | 1 |
DOIs | |
State | Published - 1 Dec 1995 |