Use of isotopic labeling in establishing reaction mechanisms: CD+                         3 + C2H6

Christian Berg; Wolfgang Wachter; Thomas Schindler; Christian Kronseder; Gereon Niedner-Schatteburg; Vladimir E. Bondybey; Zdenek Herman

doi:10.1016/0009-2614(93)90128-N

Use of isotopic labeling in establishing reaction mechanisms: CD⁺ ₃ + C₂H₆

Christian Berg
, Wolfgang Wachter
, Thomas Schindler
, Christian Kronseder
, Gereon Niedner-Schatteburg
, Vladimir E. Bondybey
, Zdenek Herman

Chair of Physical Chemistry

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

The reaction of CD⁺ ₃ with C₂H₆ has been reinvestigated by the Fourier-transform ion cyclotron resonance technique. It proceeds, in addition to the previously observed "hydride transfer" pathway resulting in the C₂H⁺ ₅ ion, by at least two other channels. "Methylene transfer" results in the isotopic C₂H₂D⁺ ₃ ion, and "eliminative condensation" accompanied by molecular hydrogen ejection results in several C₃ ionic products. The reactions are investigated as a function of the collision energy, and their possible mechanisms are discussed.

Original language	English
Pages (from-to)	465-470
Number of pages	6
Journal	Chemical Physics Letters
Volume	216
Issue number	3-6
DOIs	https://doi.org/10.1016/0009-2614(93)90128-N
State	Published - 31 Dec 1993

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@article{0c8c63b5a86a422caab82588a77136e9,

title = "Use of isotopic labeling in establishing reaction mechanisms: CD+ 3 + C2H6",

abstract = "The reaction of CD+ 3 with C2H6 has been reinvestigated by the Fourier-transform ion cyclotron resonance technique. It proceeds, in addition to the previously observed {"}hydride transfer{"} pathway resulting in the C2H+ 5 ion, by at least two other channels. {"}Methylene transfer{"} results in the isotopic C2H2D+ 3 ion, and {"}eliminative condensation{"} accompanied by molecular hydrogen ejection results in several C3 ionic products. The reactions are investigated as a function of the collision energy, and their possible mechanisms are discussed.",

author = "Christian Berg and Wolfgang Wachter and Thomas Schindler and Christian Kronseder and Gereon Niedner-Schatteburg and Bondybey, \{Vladimir E.\} and Zdenek Herman",

note = "Funding Information: Financial support by the Fond der Chemischen In-dustrie is gratefully acknowledged.T his cooperation is part of the EC Network Programme “Structure and Reactivity of Molecular Ions”.",

year = "1993",

month = dec,

day = "31",

doi = "10.1016/0009-2614(93)90128-N",

language = "English",

volume = "216",

pages = "465--470",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier B.V.",

number = "3-6",

}

TY - JOUR

T1 - Use of isotopic labeling in establishing reaction mechanisms

T2 - CD+ 3 + C2H6

AU - Berg, Christian

AU - Wachter, Wolfgang

AU - Schindler, Thomas

AU - Kronseder, Christian

AU - Niedner-Schatteburg, Gereon

AU - Bondybey, Vladimir E.

AU - Herman, Zdenek

N1 - Funding Information: Financial support by the Fond der Chemischen In-dustrie is gratefully acknowledged.T his cooperation is part of the EC Network Programme “Structure and Reactivity of Molecular Ions”.

PY - 1993/12/31

Y1 - 1993/12/31

N2 - The reaction of CD+ 3 with C2H6 has been reinvestigated by the Fourier-transform ion cyclotron resonance technique. It proceeds, in addition to the previously observed "hydride transfer" pathway resulting in the C2H+ 5 ion, by at least two other channels. "Methylene transfer" results in the isotopic C2H2D+ 3 ion, and "eliminative condensation" accompanied by molecular hydrogen ejection results in several C3 ionic products. The reactions are investigated as a function of the collision energy, and their possible mechanisms are discussed.

AB - The reaction of CD+ 3 with C2H6 has been reinvestigated by the Fourier-transform ion cyclotron resonance technique. It proceeds, in addition to the previously observed "hydride transfer" pathway resulting in the C2H+ 5 ion, by at least two other channels. "Methylene transfer" results in the isotopic C2H2D+ 3 ion, and "eliminative condensation" accompanied by molecular hydrogen ejection results in several C3 ionic products. The reactions are investigated as a function of the collision energy, and their possible mechanisms are discussed.

UR - https://www.scopus.com/pages/publications/0008152581

U2 - 10.1016/0009-2614(93)90128-N

DO - 10.1016/0009-2614(93)90128-N

M3 - Article

AN - SCOPUS:0008152581

SN - 0009-2614

VL - 216

SP - 465

EP - 470

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 3-6

ER -

Use of isotopic labeling in establishing reaction mechanisms: CD⁺ ₃ + C₂H₆

Abstract

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