Upgrading pyrolysis oil over Ni/HZSM-5 by cascade reactions

Chen Zhao; Johannes A. Lercher

doi:10.1002/anie.201108306

Upgrading pyrolysis oil over Ni/HZSM-5 by cascade reactions

Chen Zhao, Johannes A. Lercher

Chair of Chemical Technology II

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

303 Scopus citations

Abstract

Bio-oil to hydrocarbon oil: An active, selective, and stable catalyst (Ni supported in zeolite HZSM-5) allows the conversion of a wide variety of C-O and C-O bonds in n-hexane-extracted pyrolysis oil into hydrocarbons through a cascade of hydrogenation, hydrolysis, dehydration, and dehydroaromatization reactions. Quantitative yields of C ₅-C ₉ gasoline-range hydrocarbons are obtained under mild conditions in water.

Original language	English
Pages (from-to)	5935-5940
Number of pages	6
Journal	Angewandte Chemie International Edition in English
Volume	51
Issue number	24
DOIs	https://doi.org/10.1002/anie.201108306
State	Published - 11 Jun 2012

Keywords

bio-oil
hydrocarbons
hydrodeoxygenation
hydrogenolysis
phenolic compounds

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abstract = "Bio-oil to hydrocarbon oil: An active, selective, and stable catalyst (Ni supported in zeolite HZSM-5) allows the conversion of a wide variety of C-O and C-O bonds in n-hexane-extracted pyrolysis oil into hydrocarbons through a cascade of hydrogenation, hydrolysis, dehydration, and dehydroaromatization reactions. Quantitative yields of C 5-C 9 gasoline-range hydrocarbons are obtained under mild conditions in water.",

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KW - hydrodeoxygenation

KW - hydrogenolysis

KW - phenolic compounds

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Upgrading pyrolysis oil over Ni/HZSM-5 by cascade reactions

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Keywords

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