Ultrahigh molecular weight alternating propene/ethene/ carbon monoxide terpolymers with elastic properties

Adnan S. Abu-Surrah; Gabriele Eckert; Wolfgang Pechhold; Wolfgang Wilke; Bernhard Rieger

doi:10.1002/marc.1996.030170809

Ultrahigh molecular weight alternating propene/ethene/ carbon monoxide terpolymers with elastic properties

Adnan S. Abu-Surrah
, Gabriele Eckert
, Wolfgang Pechhold
, Wolfgang Wilke
, Bernhard Rieger

University of Ulm

Research output: Contribution to journal › Article › peer-review

48 Scopus citations

Abstract

Soluble propene/ethene/CO terpolymers (EPEC) with ultrahigh molecular weight (up to 1.2 × 106 g/mol) were prepared by the use of dicationic palladium(II) phosphine catalysts and an optimized amount of water as activator. When the molar ratio of ethene/CO to propene/CO is below 50 mol-%, the terpolymers are thermoplastic elastomers with excellent properties. Above this ratio the terpolymers are crystalline thermoplastics. The ultrahigh molecular weight elastomers are highly soluble in organic solvents such as CH₂Cl₂ and CHCl₃.

Original language	English
Pages (from-to)	559-565
Number of pages	7
Journal	Macromolecular Rapid Communications
Volume	17
Issue number	8
DOIs	https://doi.org/10.1002/marc.1996.030170809
State	Published - Aug 1996
Externally published	Yes

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10.1002/marc.1996.030170809

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title = "Ultrahigh molecular weight alternating propene/ethene/ carbon monoxide terpolymers with elastic properties",

abstract = "Soluble propene/ethene/CO terpolymers (EPEC) with ultrahigh molecular weight (up to 1.2 × 106 g/mol) were prepared by the use of dicationic palladium(II) phosphine catalysts and an optimized amount of water as activator. When the molar ratio of ethene/CO to propene/CO is below 50 mol-\%, the terpolymers are thermoplastic elastomers with excellent properties. Above this ratio the terpolymers are crystalline thermoplastics. The ultrahigh molecular weight elastomers are highly soluble in organic solvents such as CH2Cl2 and CHCl3.",

author = "Abu-Surrah, \{Adnan S.\} and Gabriele Eckert and Wolfgang Pechhold and Wolfgang Wilke and Bernhard Rieger",

year = "1996",

month = aug,

doi = "10.1002/marc.1996.030170809",

language = "English",

volume = "17",

pages = "559--565",

journal = "Macromolecular Rapid Communications",

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publisher = "Wiley-VCH Verlag",

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T1 - Ultrahigh molecular weight alternating propene/ethene/ carbon monoxide terpolymers with elastic properties

AU - Abu-Surrah, Adnan S.

AU - Eckert, Gabriele

AU - Pechhold, Wolfgang

AU - Wilke, Wolfgang

AU - Rieger, Bernhard

PY - 1996/8

Y1 - 1996/8

N2 - Soluble propene/ethene/CO terpolymers (EPEC) with ultrahigh molecular weight (up to 1.2 × 106 g/mol) were prepared by the use of dicationic palladium(II) phosphine catalysts and an optimized amount of water as activator. When the molar ratio of ethene/CO to propene/CO is below 50 mol-%, the terpolymers are thermoplastic elastomers with excellent properties. Above this ratio the terpolymers are crystalline thermoplastics. The ultrahigh molecular weight elastomers are highly soluble in organic solvents such as CH2Cl2 and CHCl3.

AB - Soluble propene/ethene/CO terpolymers (EPEC) with ultrahigh molecular weight (up to 1.2 × 106 g/mol) were prepared by the use of dicationic palladium(II) phosphine catalysts and an optimized amount of water as activator. When the molar ratio of ethene/CO to propene/CO is below 50 mol-%, the terpolymers are thermoplastic elastomers with excellent properties. Above this ratio the terpolymers are crystalline thermoplastics. The ultrahigh molecular weight elastomers are highly soluble in organic solvents such as CH2Cl2 and CHCl3.

UR - https://www.scopus.com/pages/publications/0030519633

U2 - 10.1002/marc.1996.030170809

DO - 10.1002/marc.1996.030170809

M3 - Article

AN - SCOPUS:0030519633

SN - 1022-1336

VL - 17

SP - 559

EP - 565

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

IS - 8

ER -

Ultrahigh molecular weight alternating propene/ethene/ carbon monoxide terpolymers with elastic properties

Abstract

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