Twelve one-electron ligands coordinating one metal center: Structure and bonding of [Mo(ZnCH3)9(ZnCp*)3]

Thomas Cadenbach; Timo Bollermann; Christian Gemel; Israel Fernandez; Moritz Von Hopffgarten; Gernot Frenking; Roland A. Fischer

doi:10.1002/anie.200802811

Twelve one-electron ligands coordinating one metal center: Structure and bonding of [Mo(ZnCH₃)₉(ZnCp*)₃]

Thomas Cadenbach, Timo Bollermann, Christian Gemel, Israel Fernandez, Moritz Von Hopffgarten, Gernot Frenking, Roland A. Fischer

Research output: Contribution to journal › Article › peer-review

75 Scopus citations

Abstract

Surrounded by zinc: The reaction of [Mo-(GaCp*)₆] and Zn(CH₃)₂ zinc yields the exceptionally high-coordinate title compound (see picture; Mo red, Zn green, C gray). Quantum chemical analysis reveals a unique bonding situation best described as a perfectly sd⁵ hybridized molybdenum atom with 12 valence electrons engagedin Mo-Zn bonding. Another six electrons are delocalized over the Zn cage, evoking only weak Zn-Zn interactions. (Figure Presented).

Original language	English
Pages (from-to)	9150-9154
Number of pages	5
Journal	Angewandte Chemie International Edition in English
Volume	47
Issue number	47
DOIs	https://doi.org/10.1002/anie.200802811
State	Published - 10 Nov 2008
Externally published	Yes

Keywords

Cluster compounds
Coordination chemistry
Gallium
Molybdenum
Zinc

Access to Document

10.1002/anie.200802811

Cite this

@article{a8eeb336addb46c0a70b016fc898f21f,

title = "Twelve one-electron ligands coordinating one metal center: Structure and bonding of [Mo(ZnCH3)9(ZnCp*)3]",

abstract = "Surrounded by zinc: The reaction of [Mo-(GaCp*)6] and Zn(CH3)2 zinc yields the exceptionally high-coordinate title compound (see picture; Mo red, Zn green, C gray). Quantum chemical analysis reveals a unique bonding situation best described as a perfectly sd5 hybridized molybdenum atom with 12 valence electrons engagedin Mo-Zn bonding. Another six electrons are delocalized over the Zn cage, evoking only weak Zn-Zn interactions. (Figure Presented).",

keywords = "Cluster compounds, Coordination chemistry, Gallium, Molybdenum, Zinc",

author = "Thomas Cadenbach and Timo Bollermann and Christian Gemel and Israel Fernandez and \{Von Hopffgarten\}, Moritz and Gernot Frenking and Fischer, \{Roland A.\}",

year = "2008",

month = nov,

day = "10",

doi = "10.1002/anie.200802811",

language = "English",

volume = "47",

pages = "9150--9154",

journal = "Angewandte Chemie International Edition in English",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "47",

}

TY - JOUR

T1 - Twelve one-electron ligands coordinating one metal center

T2 - Structure and bonding of [Mo(ZnCH3)9(ZnCp*)3]

AU - Cadenbach, Thomas

AU - Bollermann, Timo

AU - Gemel, Christian

AU - Fernandez, Israel

AU - Von Hopffgarten, Moritz

AU - Frenking, Gernot

AU - Fischer, Roland A.

PY - 2008/11/10

Y1 - 2008/11/10

N2 - Surrounded by zinc: The reaction of [Mo-(GaCp*)6] and Zn(CH3)2 zinc yields the exceptionally high-coordinate title compound (see picture; Mo red, Zn green, C gray). Quantum chemical analysis reveals a unique bonding situation best described as a perfectly sd5 hybridized molybdenum atom with 12 valence electrons engagedin Mo-Zn bonding. Another six electrons are delocalized over the Zn cage, evoking only weak Zn-Zn interactions. (Figure Presented).

AB - Surrounded by zinc: The reaction of [Mo-(GaCp*)6] and Zn(CH3)2 zinc yields the exceptionally high-coordinate title compound (see picture; Mo red, Zn green, C gray). Quantum chemical analysis reveals a unique bonding situation best described as a perfectly sd5 hybridized molybdenum atom with 12 valence electrons engagedin Mo-Zn bonding. Another six electrons are delocalized over the Zn cage, evoking only weak Zn-Zn interactions. (Figure Presented).

KW - Cluster compounds

KW - Coordination chemistry

KW - Gallium

KW - Molybdenum

KW - Zinc

UR - https://www.scopus.com/pages/publications/56249096183

U2 - 10.1002/anie.200802811

DO - 10.1002/anie.200802811

M3 - Article

AN - SCOPUS:56249096183

SN - 1433-7851

VL - 47

SP - 9150

EP - 9154

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 47

ER -

Twelve one-electron ligands coordinating one metal center: Structure and bonding of [Mo(ZnCH₃)₉(ZnCp*)₃]

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this