Turning MIL-53(Al) redox-active by functionalization of the bridging OH-group with 1,1′-ferrocenediyl-dimethylsilane

Mikhail Meilikhov; Kirill Yusenko; Roland A. Fischer

doi:10.1021/ja903918s

Turning MIL-53(Al) redox-active by functionalization of the bridging OH-group with 1,1′-ferrocenediyl-dimethylsilane

Mikhail Meilikhov
, Kirill Yusenko
, Roland A. Fischer

Max-Planck-lnstitut für Kohlenforschung

Research output: Contribution to journal › Article › peer-review

98 Scopus citations

Abstract

(Figure Presented) The postsynthetic functionalization of the bridging OH-group between two metal centers of the secondary building units of MIL-53(Al) with 1,1′-ferrocenediyl-dimethylsilane is the proof of principle of a new, selective functionalization method of the "inorganic" part of the porous coordination polymer (PCP). The functionalized material was active in the liquid-phase oxidation of benzene to phenol as a test reaction for redox activity.

Original language	English
Pages (from-to)	9644-9645
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	28
DOIs	https://doi.org/10.1021/ja903918s
State	Published - 22 Jul 2009
Externally published	Yes

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title = "Turning MIL-53(Al) redox-active by functionalization of the bridging OH-group with 1,1′-ferrocenediyl-dimethylsilane",

abstract = "(Figure Presented) The postsynthetic functionalization of the bridging OH-group between two metal centers of the secondary building units of MIL-53(Al) with 1,1′-ferrocenediyl-dimethylsilane is the proof of principle of a new, selective functionalization method of the {"}inorganic{"} part of the porous coordination polymer (PCP). The functionalized material was active in the liquid-phase oxidation of benzene to phenol as a test reaction for redox activity.",

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AU - Meilikhov, Mikhail

AU - Yusenko, Kirill

AU - Fischer, Roland A.

PY - 2009/7/22

Y1 - 2009/7/22

N2 - (Figure Presented) The postsynthetic functionalization of the bridging OH-group between two metal centers of the secondary building units of MIL-53(Al) with 1,1′-ferrocenediyl-dimethylsilane is the proof of principle of a new, selective functionalization method of the "inorganic" part of the porous coordination polymer (PCP). The functionalized material was active in the liquid-phase oxidation of benzene to phenol as a test reaction for redox activity.

AB - (Figure Presented) The postsynthetic functionalization of the bridging OH-group between two metal centers of the secondary building units of MIL-53(Al) with 1,1′-ferrocenediyl-dimethylsilane is the proof of principle of a new, selective functionalization method of the "inorganic" part of the porous coordination polymer (PCP). The functionalized material was active in the liquid-phase oxidation of benzene to phenol as a test reaction for redox activity.

UR - https://www.scopus.com/pages/publications/67650485912

U2 - 10.1021/ja903918s

DO - 10.1021/ja903918s

M3 - Article

AN - SCOPUS:67650485912

SN - 0002-7863

VL - 131

SP - 9644

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 28

ER -

Turning MIL-53(Al) redox-active by functionalization of the bridging OH-group with 1,1′-ferrocenediyl-dimethylsilane

Abstract

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