Turning MIL-53(Al) redox-active by functionalization of the bridging OH-group with 1,1′-ferrocenediyl-dimethylsilane

Mikhail Meilikhov, Kirill Yusenko, Roland A. Fischer

Research output: Contribution to journalArticlepeer-review

91 Scopus citations

Abstract

(Figure Presented) The postsynthetic functionalization of the bridging OH-group between two metal centers of the secondary building units of MIL-53(Al) with 1,1′-ferrocenediyl-dimethylsilane is the proof of principle of a new, selective functionalization method of the "inorganic" part of the porous coordination polymer (PCP). The functionalized material was active in the liquid-phase oxidation of benzene to phenol as a test reaction for redox activity.

Original languageEnglish
Pages (from-to)9644-9645
Number of pages2
JournalJournal of the American Chemical Society
Volume131
Issue number28
DOIs
StatePublished - 22 Jul 2009
Externally publishedYes

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