Abstract
(Figure Presented) The postsynthetic functionalization of the bridging OH-group between two metal centers of the secondary building units of MIL-53(Al) with 1,1′-ferrocenediyl-dimethylsilane is the proof of principle of a new, selective functionalization method of the "inorganic" part of the porous coordination polymer (PCP). The functionalized material was active in the liquid-phase oxidation of benzene to phenol as a test reaction for redox activity.
Original language | English |
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Pages (from-to) | 9644-9645 |
Number of pages | 2 |
Journal | Journal of the American Chemical Society |
Volume | 131 |
Issue number | 28 |
DOIs | |
State | Published - 22 Jul 2009 |
Externally published | Yes |