Tuning the electronic properties of tetradentate iron-NHC complexes: Towards stable and selective epoxidation catalysts

Keyphrases

• Electronic Properties 100%
• Pd-NHC Complex 100%
• Tetradentate 100%
• Epoxidation Catalyst 100%
• Selective Epoxidation 100%
• Bio-inspired 50%
• Hydrogen Peroxide 50%
• Elemental Analysis 50%
• Structural Features 50%
• DFT Calculations 50%
• Cyclic Voltammetry 50%
• High Stability 50%
• Electronic Characteristics 50%
• Fe(II) 50%
• Functionalized Olefins 50%
• Epoxidation 50%
• Catalytic Performance 50%
• Electrospray Ionization Mass Spectrometry 50%
• Precatalyst 50%
• N-heterocyclic Carbene Ligands 50%
• Sc(OTf)3 50%
• Olefin Epoxidation 50%
• High Temperature Tolerance 50%
• Fe(III) 50%
• AcOH 50%
• Non-heme Iron 50%
• Terminal Olefins 50%
• Acid Additives 50%
• Single Crystal X-ray Diffraction (SCXRD) 50%
• Labile Coordination Sites 50%

Chemistry

• Electronic Property 100%
• epoxidation 100%
• Alkene 66%
• Elemental Analysis 33%
• Cyclic Voltammetry 33%
• Iron Complex 33%
• X-Ray Diffraction 33%
• N-Heterocyclic Carbene 33%
• Electrospray Ionization Mass Spectroscopy 33%
• Hydrogen Peroxide 33%
• NMR Spectroscopy 33%
• Density Functional Theory 33%
• electronics 33%
• pre-catalyst 33%
• Heme Iron 33%

Chemical Engineering

• Olefin 100%
• Hydrogen Peroxide 50%
• Chemical Element 50%
• Discrete Fourier Transform 50%