Abstract
Silyl esters of perrhenic acid of the type R3SiOReO3 have been found to be thermally stable and readily accessible. Reaction of silver perrhenate with chlorotrimethylsilane in hexamethyldisiloxane as well as the reaction of rhenium heptoxide with hexamethyldisiloxane are reported to produce R3SiOReO3 in good yields.
Original language | English |
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Title of host publication | Efficient Methods for Preparing Silicon Compounds |
Publisher | Elsevier Inc. |
Pages | 21-25 |
Number of pages | 5 |
ISBN (Electronic) | 9780128035689 |
ISBN (Print) | 9780128035306 |
DOIs | |
State | Published - 31 May 2016 |
Keywords
- Chlorotrimethylsilane
- Hexamethyldisiloxane
- Rhenium heptoxide
- Silver perrhenate
- Silyl esters
- Trimethylsilyl perrhenate