Trimethylsilyl Perrhenate-A Nonionic Reagent Soluble in Organic Solvents for the Preparation of Perrhenates

H. Schmidbaur

Research output: Chapter in Book/Report/Conference proceedingChapterpeer-review

1 Scopus citations

Abstract

Silyl esters of perrhenic acid of the type R3SiOReO3 have been found to be thermally stable and readily accessible. Reaction of silver perrhenate with chlorotrimethylsilane in hexamethyldisiloxane as well as the reaction of rhenium heptoxide with hexamethyldisiloxane are reported to produce R3SiOReO3 in good yields.

Original languageEnglish
Title of host publicationEfficient Methods for Preparing Silicon Compounds
PublisherElsevier Inc.
Pages21-25
Number of pages5
ISBN (Electronic)9780128035689
ISBN (Print)9780128035306
DOIs
StatePublished - 31 May 2016
Externally publishedYes

Keywords

  • Chlorotrimethylsilane
  • Hexamethyldisiloxane
  • Rhenium heptoxide
  • Silver perrhenate
  • Silyl esters
  • Trimethylsilyl perrhenate

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