Trialkylaluminum N-Heterocyclic Olefin (NHO) Adducts as Catalysts for the Polymerization of Michael-Type Monomers

Ian C. Watson; Yuqiao Zhou; Michael J. Ferguson; Moritz Kränzlein; Bernhard Rieger; Eric Rivard

doi:10.1002/zaac.201900331

Trialkylaluminum N-Heterocyclic Olefin (NHO) Adducts as Catalysts for the Polymerization of Michael-Type Monomers

Ian C. Watson
, Yuqiao Zhou
, Michael J. Ferguson
, Moritz Kränzlein
, Bernhard Rieger
, Eric Rivard

Wacker-Chair of Macromolecular Chemistry

University of Alberta
Technical University of Munich

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The synthesis of new trialkylaluminum adducts with N-heterocyclic olefin (NHO) ligands is described. These well-defined complexes can catalyze the polymerization of various Michael-type monomers, such as 2-vinylpyridine, methylacrylate, and dimethylacrylamide.

Original language	English
Pages (from-to)	547-551
Number of pages	5
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	646
Issue number	13
DOIs	https://doi.org/10.1002/zaac.201900331
State	Published - 15 Jul 2020

Keywords

Aluminum
Frustrated Lewis pairs
Michael-type monomers
N-Heterocyclic olefins
Polymerization

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10.1002/zaac.201900331

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title = "Trialkylaluminum N-Heterocyclic Olefin (NHO) Adducts as Catalysts for the Polymerization of Michael-Type Monomers",

abstract = "The synthesis of new trialkylaluminum adducts with N-heterocyclic olefin (NHO) ligands is described. These well-defined complexes can catalyze the polymerization of various Michael-type monomers, such as 2-vinylpyridine, methylacrylate, and dimethylacrylamide.",

keywords = "Aluminum, Frustrated Lewis pairs, Michael-type monomers, N-Heterocyclic olefins, Polymerization",

author = "Watson, \{Ian C.\} and Yuqiao Zhou and Ferguson, \{Michael J.\} and Moritz Kr{\"a}nzlein and Bernhard Rieger and Eric Rivard",

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year = "2020",

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doi = "10.1002/zaac.201900331",

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T1 - Trialkylaluminum N-Heterocyclic Olefin (NHO) Adducts as Catalysts for the Polymerization of Michael-Type Monomers

AU - Watson, Ian C.

AU - Zhou, Yuqiao

AU - Ferguson, Michael J.

AU - Kränzlein, Moritz

AU - Rieger, Bernhard

AU - Rivard, Eric

PY - 2020/7/15

Y1 - 2020/7/15

N2 - The synthesis of new trialkylaluminum adducts with N-heterocyclic olefin (NHO) ligands is described. These well-defined complexes can catalyze the polymerization of various Michael-type monomers, such as 2-vinylpyridine, methylacrylate, and dimethylacrylamide.

AB - The synthesis of new trialkylaluminum adducts with N-heterocyclic olefin (NHO) ligands is described. These well-defined complexes can catalyze the polymerization of various Michael-type monomers, such as 2-vinylpyridine, methylacrylate, and dimethylacrylamide.

KW - Aluminum

KW - Frustrated Lewis pairs

KW - Michael-type monomers

KW - N-Heterocyclic olefins

KW - Polymerization

UR - https://www.scopus.com/pages/publications/85079384824

U2 - 10.1002/zaac.201900331

DO - 10.1002/zaac.201900331

M3 - Article

AN - SCOPUS:85079384824

SN - 0044-2313

VL - 646

SP - 547

EP - 551

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 13

ER -

Trialkylaluminum N-Heterocyclic Olefin (NHO) Adducts as Catalysts for the Polymerization of Michael-Type Monomers

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Keywords

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