Transformation of nickelalactones to methyl acrylate: On the way to a catalytic conversion of carbon dioxide

S. Y.Tina Lee; Mirza Cokoja; Markus Drees; Yang Li; János Mink; Wolfgang A. Herrmann; Fritz E. Kühn

doi:10.1002/cssc.201000445

Transformation of nickelalactones to methyl acrylate: On the way to a catalytic conversion of carbon dioxide

S. Y.Tina Lee, Mirza Cokoja, Markus Drees, Yang Li, János Mink, Wolfgang A. Herrmann, Fritz E. Kühn

Research output: Contribution to journal › Article › peer-review

66 Scopus citations

Abstract

Mu-nick: The methyl iodide-mediated ring opening of nickelalactones, which can be formed by oxidative coupling of carbon dioxide and ethylene at Ni ⁰ complexes, induces β-H elimination, producing methyl acrylate in yields of up to 56 %. This reaction is found to be very sensitive to the ligands coordinated to the central nickel atom.

Original language	English
Pages (from-to)	1275-1279
Number of pages	5
Journal	ChemSusChem
Volume	4
Issue number	9
DOIs	https://doi.org/10.1002/cssc.201000445
State	Published - 19 Sep 2011

Keywords

acrylic acid
carbon dioxide fixation
homogeneous catalysis
ligand effects
nickel

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10.1002/cssc.201000445

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abstract = "Mu-nick: The methyl iodide-mediated ring opening of nickelalactones, which can be formed by oxidative coupling of carbon dioxide and ethylene at Ni 0 complexes, induces β-H elimination, producing methyl acrylate in yields of up to 56 \%. This reaction is found to be very sensitive to the ligands coordinated to the central nickel atom.",

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AU - Lee, S. Y.Tina

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AU - Drees, Markus

AU - Li, Yang

AU - Mink, János

AU - Herrmann, Wolfgang A.

AU - Kühn, Fritz E.

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KW - acrylic acid

KW - carbon dioxide fixation

KW - homogeneous catalysis

KW - ligand effects

KW - nickel

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Transformation of nickelalactones to methyl acrylate: On the way to a catalytic conversion of carbon dioxide

Abstract

Keywords

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