Transferring photocatalytic CO2reduction mediated by Cu(N^N)(P^P)+complexes from organic solvents into ionic liquid media

Paola A. Forero-Cortés; Maximilian Marx; Nikolaos G. Moustakas; Fabian Brunner; Catherine E. Housecroft; Edwin C. Constable; Henrik Junge; Matthias Beller; Jennifer Strunk

doi:10.1039/d0gc01627f

Transferring photocatalytic CO₂reduction mediated by Cu(N^N)(P^P)⁺complexes from organic solvents into ionic liquid media

Paola A. Forero-Cortés
, Maximilian Marx
, Nikolaos G. Moustakas
, Fabian Brunner
, Catherine E. Housecroft
, Edwin C. Constable
, Henrik Junge
, Matthias Beller
, Jennifer Strunk

Leibniz-Institut für Katalyse
University of St Andrews
University of Basel

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

Photocatalytic carbon dioxide reduction utilizing metal complexes based on the earth-abundant transition metals iron and copper was transferred from organic solvents into ionic liquids with high selectivity and moderate turn-over numbers. Different classes of ionic liquids were evaluated to determinate the CO/H2 selectivity of the process. High-purity conditions were utilized to validate that CO was a result of CO2 reduction and not resulting from other carbon sources. In addition, a novel copper-based photosensitizer was synthesized and its photo- and electrochemical properties were investigated.

Original language	English
Pages (from-to)	4541-4549
Number of pages	9
Journal	Green Chemistry
Volume	22
Issue number	14
DOIs	https://doi.org/10.1039/d0gc01627f
State	Published - 21 Jul 2020
Externally published	Yes

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10.1039/d0gc01627f

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title = "Transferring photocatalytic CO2reduction mediated by Cu(N\textasciicircum{}N)(P\textasciicircum{}P)+complexes from organic solvents into ionic liquid media",

abstract = "Photocatalytic carbon dioxide reduction utilizing metal complexes based on the earth-abundant transition metals iron and copper was transferred from organic solvents into ionic liquids with high selectivity and moderate turn-over numbers. Different classes of ionic liquids were evaluated to determinate the CO/H2 selectivity of the process. High-purity conditions were utilized to validate that CO was a result of CO2 reduction and not resulting from other carbon sources. In addition, a novel copper-based photosensitizer was synthesized and its photo- and electrochemical properties were investigated.",

author = "Forero-Cort{\'e}s, \{Paola A.\} and Maximilian Marx and Moustakas, \{Nikolaos G.\} and Fabian Brunner and Housecroft, \{Catherine E.\} and Constable, \{Edwin C.\} and Henrik Junge and Matthias Beller and Jennifer Strunk",

note = "Publisher Copyright: {\textcopyright} 2020 The Royal Society of Chemistry.",

year = "2020",

month = jul,

day = "21",

doi = "10.1039/d0gc01627f",

language = "English",

volume = "22",

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journal = "Green Chemistry",

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publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Transferring photocatalytic CO2reduction mediated by Cu(N^N)(P^P)+complexes from organic solvents into ionic liquid media

AU - Forero-Cortés, Paola A.

AU - Marx, Maximilian

AU - Moustakas, Nikolaos G.

AU - Brunner, Fabian

AU - Housecroft, Catherine E.

AU - Constable, Edwin C.

AU - Junge, Henrik

AU - Beller, Matthias

AU - Strunk, Jennifer

PY - 2020/7/21

Y1 - 2020/7/21

N2 - Photocatalytic carbon dioxide reduction utilizing metal complexes based on the earth-abundant transition metals iron and copper was transferred from organic solvents into ionic liquids with high selectivity and moderate turn-over numbers. Different classes of ionic liquids were evaluated to determinate the CO/H2 selectivity of the process. High-purity conditions were utilized to validate that CO was a result of CO2 reduction and not resulting from other carbon sources. In addition, a novel copper-based photosensitizer was synthesized and its photo- and electrochemical properties were investigated.

AB - Photocatalytic carbon dioxide reduction utilizing metal complexes based on the earth-abundant transition metals iron and copper was transferred from organic solvents into ionic liquids with high selectivity and moderate turn-over numbers. Different classes of ionic liquids were evaluated to determinate the CO/H2 selectivity of the process. High-purity conditions were utilized to validate that CO was a result of CO2 reduction and not resulting from other carbon sources. In addition, a novel copper-based photosensitizer was synthesized and its photo- and electrochemical properties were investigated.

UR - https://www.scopus.com/pages/publications/85094210088

U2 - 10.1039/d0gc01627f

DO - 10.1039/d0gc01627f

M3 - Article

AN - SCOPUS:85094210088

SN - 1463-9262

VL - 22

SP - 4541

EP - 4549

JO - Green Chemistry

JF - Green Chemistry

IS - 14

ER -

Transferring photocatalytic CO₂reduction mediated by Cu(N^N)(P^P)⁺complexes from organic solvents into ionic liquid media

Abstract

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