Abstract
Protocols for preparative (1-80 gram scale) transfer hydrogenations of alkenes over a palladium on carbon catalyst using formic acid/ammonium formate as hydrogen donor are presented. Cinchona alkaloids have been converted to their dihydro derivatives in >94% yield.
| Original language | English |
|---|---|
| Article number | SS-2013-Z0022-PSP |
| Pages (from-to) | 888-892 |
| Number of pages | 5 |
| Journal | Synthesis |
| Volume | 45 |
| Issue number | 7 |
| DOIs | |
| State | Published - 2013 |
Keywords
- alkaloids
- alkenes
- catalysis
- hydrogen transfer
- hydrogenation
- palladium
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