Tracer diffusion in lattice gases

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Abstract

It has been proved that a tracer particle in a reversible lattice gas converges to Brownian motion. However, only in a few particular cases has a strictly positive self-diffusion coefficient D been established. Here we supply the missing piece and show that D>0 in general. The exceptions are one-dimensional lattice gases with nearest neighbor jumps only, for which D=0. The proof establishes a variational formula for D which could be used to obtain realistic bounds.

Original languageEnglish
Pages (from-to)1227-1239
Number of pages13
JournalJournal of Statistical Physics
Volume59
Issue number5-6
DOIs
StatePublished - Jun 1990
Externally publishedYes

Keywords

  • Stochastic lattice gases
  • self-diffusion
  • variational formula

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