TY - JOUR
T1 - Towards Organic Zeolites and Inclusion Catalysts
T2 - Heptazine Imide Salts Can Exchange Metal Cations in the Solid State
AU - Savateev, Aleksandr
AU - Pronkin, Sergey
AU - Willinger, Marc Georg
AU - Antonietti, Markus
AU - Dontsova, Dariya
N1 - Publisher Copyright:
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
PY - 2017/7/4
Y1 - 2017/7/4
N2 - Highly crystalline potassium (heptazine imides) were prepared by the thermal condensation of substituted 1,2,4-triazoles in eutectic salt melts. These semiconducting salts are already known to be highly active photocatalysts, for example, for the visible-light-driven generation of hydrogen from water. Herein, we show that within the solid-state structure, potassium ions can be exchanged to other metal ions while the crystal habitus is essentially preserved.
AB - Highly crystalline potassium (heptazine imides) were prepared by the thermal condensation of substituted 1,2,4-triazoles in eutectic salt melts. These semiconducting salts are already known to be highly active photocatalysts, for example, for the visible-light-driven generation of hydrogen from water. Herein, we show that within the solid-state structure, potassium ions can be exchanged to other metal ions while the crystal habitus is essentially preserved.
KW - carbon nitride
KW - eutectic salt melts
KW - organic zeolites
KW - poly(heptazine imide)
KW - porous solid polyelectrolytes
UR - http://www.scopus.com/inward/record.url?scp=85016067115&partnerID=8YFLogxK
U2 - 10.1002/asia.201700209
DO - 10.1002/asia.201700209
M3 - Article
C2 - 28199049
AN - SCOPUS:85016067115
SN - 1861-4728
VL - 12
SP - 1517
EP - 1522
JO - Chemistry - An Asian Journal
JF - Chemistry - An Asian Journal
IS - 13
ER -