Toward Chiral sum-frequency spectroscopy

Na Ji; Victor Ostroverkhov; Mikhail Belkin; Ying Jen Shiu; Yuen Ron Shen

doi:10.1021/ja060888c

Toward Chiral sum-frequency spectroscopy

Na Ji, Victor Ostroverkhov, Mikhail Belkin, Ying Jen Shiu, Yuen Ron Shen

University of California at Berkeley

Research output: Contribution to journal › Article › peer-review

46 Scopus citations

Abstract

Chiral sum-frequency (SF) spectroscopy that measures both the real and the imaginary components of the SF spectral response was demonstrated for the first time. It was based on interference of the SF signal with a dispersionless SF reference. Solutions of 1,1′-bi-2-naphthol (BN) were used as model systems, and their chiral SF spectra over the first exciton-split transitions were obtained. Chiral spectra are useful for determination of absolute configuration and conformation of chiral molecules.

Original language	English
Pages (from-to)	8845-8848
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	128
Issue number	27
DOIs	https://doi.org/10.1021/ja060888c
State	Published - 12 Jul 2006
Externally published	Yes

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10.1021/ja060888c

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abstract = "Chiral sum-frequency (SF) spectroscopy that measures both the real and the imaginary components of the SF spectral response was demonstrated for the first time. It was based on interference of the SF signal with a dispersionless SF reference. Solutions of 1,1′-bi-2-naphthol (BN) were used as model systems, and their chiral SF spectra over the first exciton-split transitions were obtained. Chiral spectra are useful for determination of absolute configuration and conformation of chiral molecules.",

author = "Na Ji and Victor Ostroverkhov and Mikhail Belkin and Shiu, {Ying Jen} and Shen, {Yuen Ron}",

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AU - Ji, Na

AU - Ostroverkhov, Victor

AU - Belkin, Mikhail

AU - Shiu, Ying Jen

AU - Shen, Yuen Ron

PY - 2006/7/12

Y1 - 2006/7/12

N2 - Chiral sum-frequency (SF) spectroscopy that measures both the real and the imaginary components of the SF spectral response was demonstrated for the first time. It was based on interference of the SF signal with a dispersionless SF reference. Solutions of 1,1′-bi-2-naphthol (BN) were used as model systems, and their chiral SF spectra over the first exciton-split transitions were obtained. Chiral spectra are useful for determination of absolute configuration and conformation of chiral molecules.

AB - Chiral sum-frequency (SF) spectroscopy that measures both the real and the imaginary components of the SF spectral response was demonstrated for the first time. It was based on interference of the SF signal with a dispersionless SF reference. Solutions of 1,1′-bi-2-naphthol (BN) were used as model systems, and their chiral SF spectra over the first exciton-split transitions were obtained. Chiral spectra are useful for determination of absolute configuration and conformation of chiral molecules.

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Toward Chiral sum-frequency spectroscopy

Abstract

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