Thioalkylierung der Metall–Kohlenstoff‐Mehrfachbindung in Carbin‐ und Carben‐Komplexen von Molybdän und Wolfram

Fritz R. Kreißl, Wolfgang Schütt, Claudia M. Stegmair, Norbert Ullrich, Hans Keller, Josef Ostermeier, Eberhardt Herdtweck

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Thiomethylation of the Metal–Carbon Multiple Bond of Carbyne and Carbene Complexes of Molybdenum and Tungsten Carbyne complexes of molybdenum and tungsten react with dialkyl(methylthio)sulfonium tetrafluoroborate in a stepwise addition of the alkylthio cation to the metal–carbon multiple bond yielding dicationic η3‐dithiomethyl complexes.

Original languageGerman
Pages (from-to)1609-1614
Number of pages6
JournalChemische Berichte
Issue number7
StatePublished - Jul 1993

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