Thermal-cycling-induced spectral diffusion and thermal barriers in anisole-doped cyclohexane, an unusual multiphase host-guest system

Mark M. Somoza, Josef Friedrich

Research output: Contribution to journalArticlepeer-review

Abstract

The host-guest system of anisole incorporated into a cyclohexane matrix was investigated in a series of hole-burning experiments. This system is unusual in that cyclohexane can freeze into coexisting solid phases. The hole-burning experiments support the existence of two crystalline phases and one disordered phase. A second surprising characteristic of this system is that the quasi-line absorption features of the spectra appear inverted at low temperature because of unexpected dominance of fluorescence and phosphorescence.

Original languageEnglish
Pages (from-to)18828-18833
Number of pages6
JournalJournal of Physical Chemistry B
Volume110
Issue number38
DOIs
StatePublished - 28 Sep 2006

Fingerprint

Dive into the research topics of 'Thermal-cycling-induced spectral diffusion and thermal barriers in anisole-doped cyclohexane, an unusual multiphase host-guest system'. Together they form a unique fingerprint.

Cite this