Abstract
The host-guest system of anisole incorporated into a cyclohexane matrix was investigated in a series of hole-burning experiments. This system is unusual in that cyclohexane can freeze into coexisting solid phases. The hole-burning experiments support the existence of two crystalline phases and one disordered phase. A second surprising characteristic of this system is that the quasi-line absorption features of the spectra appear inverted at low temperature because of unexpected dominance of fluorescence and phosphorescence.
Original language | English |
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Pages (from-to) | 18828-18833 |
Number of pages | 6 |
Journal | Journal of Physical Chemistry B |
Volume | 110 |
Issue number | 38 |
DOIs | |
State | Published - 28 Sep 2006 |