The Transylidation Reaction of Zirconium tetrachloride with Phosphonium Ylides: Structure of M ethyl-tris(diethylamino)-phosphonium Hexachlorozirconate

Hubert Schmidbaur; Reinhard Pichl; Gerhard Müller

doi:10.1515/znb-1986-0318

The Transylidation Reaction of Zirconium tetrachloride with Phosphonium Ylides: Structure of M ethyl-tris(diethylamino)-phosphonium Hexachlorozirconate

Hubert Schmidbaur, Reinhard Pichl, Gerhard Müller

Technical University of Munich

Research output: Contribution to journal › Comment/debate

16 Scopus citations

Abstract

The reaction between ZrCl₄ and (Et₂N)₃P = CH₂ affords the zirconium-substituted ylide [(Et₂N)₃PCZrCl₂]₂ (1). The transylidation by-pro-duct [(Et₂N)₃PCH₃]Cl is trapped by excess ZrCl₄ to give the complex salt [(Et₂N)₃PCH₃]₂ZrCl₆(2) the structure of which was determined by single crystal X-ray diffraction.

Translated title of the contribution	Die Umylidierungsreaktion Von Zirkoniumtetrachlorid Mit Phosphonium-Yliden: Struktur Von Methyl-Tris(Diethylamino)-Phosphonium-Hexachlorozirkonat
Original language	English
Pages (from-to)	395-398
Number of pages	4
Journal	Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume	41
Issue number	3
DOIs	https://doi.org/10.1515/znb-1986-0318
State	Published - 1 Mar 1986
Externally published	Yes

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title = "The Transylidation Reaction of Zirconium tetrachloride with Phosphonium Ylides: Structure of M ethyl-tris(diethylamino)-phosphonium Hexachlorozirconate",

abstract = "The reaction between ZrCl4 and (Et2N)3P = CH2 affords the zirconium-substituted ylide [(Et2N)3PCZrCl2]2 (1). The transylidation by-pro-duct [(Et2N)3PCH3]Cl is trapped by excess ZrCl4 to give the complex salt [(Et2N)3PCH3]2ZrCl6(2) the structure of which was determined by single crystal X-ray diffraction.",

author = "Hubert Schmidbaur and Reinhard Pichl and Gerhard M{\"u}ller",

year = "1986",

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doi = "10.1515/znb-1986-0318",

language = "English",

volume = "41",

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journal = "Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences",

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publisher = "Walter de Gruyter GmbH",

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}

The Transylidation Reaction of Zirconium tetrachloride with Phosphonium Ylides: Structure of M ethyl-tris(diethylamino)-phosphonium Hexachlorozirconate. / Schmidbaur, Hubert; Pichl, Reinhard; Müller, Gerhard.
In: Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, Vol. 41, No. 3, 01.03.1986, p. 395-398.

Research output: Contribution to journal › Comment/debate

TY - JOUR

T1 - The Transylidation Reaction of Zirconium tetrachloride with Phosphonium Ylides

T2 - Structure of M ethyl-tris(diethylamino)-phosphonium Hexachlorozirconate

AU - Schmidbaur, Hubert

AU - Pichl, Reinhard

AU - Müller, Gerhard

PY - 1986/3/1

Y1 - 1986/3/1

N2 - The reaction between ZrCl4 and (Et2N)3P = CH2 affords the zirconium-substituted ylide [(Et2N)3PCZrCl2]2 (1). The transylidation by-pro-duct [(Et2N)3PCH3]Cl is trapped by excess ZrCl4 to give the complex salt [(Et2N)3PCH3]2ZrCl6(2) the structure of which was determined by single crystal X-ray diffraction.

AB - The reaction between ZrCl4 and (Et2N)3P = CH2 affords the zirconium-substituted ylide [(Et2N)3PCZrCl2]2 (1). The transylidation by-pro-duct [(Et2N)3PCH3]Cl is trapped by excess ZrCl4 to give the complex salt [(Et2N)3PCH3]2ZrCl6(2) the structure of which was determined by single crystal X-ray diffraction.

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U2 - 10.1515/znb-1986-0318

DO - 10.1515/znb-1986-0318

M3 - Comment/debate

AN - SCOPUS:84955837386

SN - 0932-0776

VL - 41

SP - 395

EP - 398

JO - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

JF - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

IS - 3

ER -

The Transylidation Reaction of Zirconium tetrachloride with Phosphonium Ylides: Structure of M ethyl-tris(diethylamino)-phosphonium Hexachlorozirconate

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