The selective catalytic oxidation of terminal alcohols: A novel four-component system with MTO as catalyst

Wolfgang A. Herrmann; Jochen P. Zoller; Richard W. Fischer

doi:10.1016/S0022-328X(99)00013-3

The selective catalytic oxidation of terminal alcohols: A novel four-component system with MTO as catalyst

Technical University of Munich

Technical University of Munich
Celanese GmbH - Werk Ruhrchemie

Research output: Contribution to journal › Article › peer-review

51 Scopus citations

Abstract

A four-component system (H₂O₂, MTO, HBr, TEMPO) in acetic acid catalyzes the selective oxidation of terminal alcohols to the corresponding aldehydes with excellent selectivity and yield. The system allows the oxidation of alcohols with hydrogen peroxide as oxidants either selectively to aldehydes or to the corresponding acids, depending on the reaction parameters. The new technique is especially applicable to the oxidation of carbohydrates.

Original language	English
Pages (from-to)	404-407
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	579
Issue number	1-2
DOIs	https://doi.org/10.1016/S0022-328X(99)00013-3
State	Published - 5 May 1999

Keywords

Carbohydrates
Catalysis
HBr
Methyltrioxorhenium
Oxidation
Renewable resources
Starch
TEMPO

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10.1016/S0022-328X(99)00013-3

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title = "The selective catalytic oxidation of terminal alcohols: A novel four-component system with MTO as catalyst",

abstract = "A four-component system (H2O2, MTO, HBr, TEMPO) in acetic acid catalyzes the selective oxidation of terminal alcohols to the corresponding aldehydes with excellent selectivity and yield. The system allows the oxidation of alcohols with hydrogen peroxide as oxidants either selectively to aldehydes or to the corresponding acids, depending on the reaction parameters. The new technique is especially applicable to the oxidation of carbohydrates.",

keywords = "Carbohydrates, Catalysis, HBr, Methyltrioxorhenium, Oxidation, Renewable resources, Starch, TEMPO",

author = "Herrmann, \{Wolfgang A.\} and Zoller, \{Jochen P.\} and Fischer, \{Richard W.\}",

note = "Funding Information: The authors are grateful to their coworkers J.-O. Barth and M. Hoffmann for support. This work was generously supported by the {\textquoteleft}Bayerischer Forschungsverbund Katalyse{\textquoteright} and the Bavarian Ministry of Nutrition, Agriculture and Forestry (grants for J.P. Zoller).",

year = "1999",

month = may,

day = "5",

doi = "10.1016/S0022-328X(99)00013-3",

language = "English",

volume = "579",

pages = "404--407",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "1-2",

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TY - JOUR

T1 - The selective catalytic oxidation of terminal alcohols

T2 - A novel four-component system with MTO as catalyst

AU - Herrmann, Wolfgang A.

AU - Zoller, Jochen P.

AU - Fischer, Richard W.

N1 - Funding Information: The authors are grateful to their coworkers J.-O. Barth and M. Hoffmann for support. This work was generously supported by the ‘Bayerischer Forschungsverbund Katalyse’ and the Bavarian Ministry of Nutrition, Agriculture and Forestry (grants for J.P. Zoller).

PY - 1999/5/5

Y1 - 1999/5/5

N2 - A four-component system (H2O2, MTO, HBr, TEMPO) in acetic acid catalyzes the selective oxidation of terminal alcohols to the corresponding aldehydes with excellent selectivity and yield. The system allows the oxidation of alcohols with hydrogen peroxide as oxidants either selectively to aldehydes or to the corresponding acids, depending on the reaction parameters. The new technique is especially applicable to the oxidation of carbohydrates.

AB - A four-component system (H2O2, MTO, HBr, TEMPO) in acetic acid catalyzes the selective oxidation of terminal alcohols to the corresponding aldehydes with excellent selectivity and yield. The system allows the oxidation of alcohols with hydrogen peroxide as oxidants either selectively to aldehydes or to the corresponding acids, depending on the reaction parameters. The new technique is especially applicable to the oxidation of carbohydrates.

KW - Carbohydrates

KW - Catalysis

KW - HBr

KW - Methyltrioxorhenium

KW - Oxidation

KW - Renewable resources

KW - Starch

KW - TEMPO

UR - https://www.scopus.com/pages/publications/0000740208

U2 - 10.1016/S0022-328X(99)00013-3

DO - 10.1016/S0022-328X(99)00013-3

M3 - Article

AN - SCOPUS:0000740208

SN - 0022-328X

VL - 579

SP - 404

EP - 407

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

The selective catalytic oxidation of terminal alcohols: A novel four-component system with MTO as catalyst

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Keywords

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