The retarded van der Waals potential

Tadahiro Miyao, Herbert Spohn

Research output: Contribution to journalArticlepeer-review

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Abstract

The retarded van der Waals potential, as first obtained by Casimir and Polder, is usually computed on the basis of nonrelativistic quantum electrodynamics. The Hamiltonian describes two infinitely heavy nuclei, charge e, separated by a distance R and two spinless electrons, charge -e, nonrelativistically coupled to the quantized radiation field. Casimir and Polder used the dipole approximation and small coupling to the Maxwell field. We employ here the full Hamiltonian and determine the asymptotic strength of the leading - R-7 potential, which is valid for all e. Our computation is based on a path integral representation and expands in 1/R, rather than in e.

Original languageEnglish
Article number072103
JournalJournal of Mathematical Physics
Volume50
Issue number7
DOIs
StatePublished - 2009

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