TY - JOUR
T1 - The Recoil‐Free Fraction of the γ Resonance in 197Au Mössbauer Spectroscopy; Findings from Measurements of Polynuclear, Mixed‐Valent Ylide Complexes
AU - Schmidbaur, Hubert
AU - Hartmann, Christoph
AU - Wagner, Friedrich E.
PY - 1987/11
Y1 - 1987/11
N2 - The intensities of lines in 197 Au Mössbauer spectra have so far been very hard to interpret and therefore their use in structure elucidations has not been possible. Owing to the rich variety of new gold compounds in various oxidation states and with different coordination geometries, such an interpretation has now become possible. In addition to the isomeric shift (IS) and the quadrupole coupling (QS), the recoil‐free fraction (RFF) has become an important quantity for analyzing the structures of gold compounds.
AB - The intensities of lines in 197 Au Mössbauer spectra have so far been very hard to interpret and therefore their use in structure elucidations has not been possible. Owing to the rich variety of new gold compounds in various oxidation states and with different coordination geometries, such an interpretation has now become possible. In addition to the isomeric shift (IS) and the quadrupole coupling (QS), the recoil‐free fraction (RFF) has become an important quantity for analyzing the structures of gold compounds.
UR - http://www.scopus.com/inward/record.url?scp=84985630898&partnerID=8YFLogxK
U2 - 10.1002/anie.198711481
DO - 10.1002/anie.198711481
M3 - Article
AN - SCOPUS:84985630898
SN - 0570-0833
VL - 26
SP - 1148
EP - 1150
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 11
ER -