The rational design of anion host compounds: An exercise in subtle energetics

Manal Haj-Zaroubi; Norbert W. Mitzel; Franz P. Schmidtchen

doi:10.1002/1521-3773(20020104)41:1<104::AID-ANIE104>3.0.CO;2-Z

The rational design of anion host compounds: An exercise in subtle energetics

Manal Haj-Zaroubi
, Norbert W. Mitzel
, Franz P. Schmidtchen

Natural Sciences

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

80 Scopus citations

Abstract

Lock-and-key binding is an inadequate description for the molecular-recognition interaction of guanidinium cations and carboxylates in acetonitrile (see picture) as shown by direct calorimetric determinations in a tailored series of host-guest pairs.

Original language	English
Pages (from-to)	104-107
Number of pages	4
Journal	Angewandte Chemie International Edition in English
Volume	41
Issue number	1
DOIs	https://doi.org/10.1002/1521-3773(20020104)41:1<104::AID-ANIE104>3.0.CO;2-Z
State	Published - 4 Jan 2002

Keywords

Bond enthalpy
Calorimetry
Host-guest systems
Molecular recognition
Nitrogen heterocycles

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10.1002/1521-3773(20020104)41:1<104::AID-ANIE104>3.0.CO;2-Z

Cite this

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abstract = "Lock-and-key binding is an inadequate description for the molecular-recognition interaction of guanidinium cations and carboxylates in acetonitrile (see picture) as shown by direct calorimetric determinations in a tailored series of host-guest pairs.",

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KW - Bond enthalpy

KW - Calorimetry

KW - Host-guest systems

KW - Molecular recognition

KW - Nitrogen heterocycles

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The rational design of anion host compounds: An exercise in subtle energetics

Abstract

Keywords

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