The Next Generation of Silylene Ligands for Better Catalysts

Shigeyoshi Inoue

doi:10.1002/9783527673223.ch10

The Next Generation of Silylene Ligands for Better Catalysts

Shigeyoshi Inoue

Technische Universität Berlin

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

7 Scopus citations

Abstract

Silylenes are very versatile ligands and the heavier analog of the better known carbenes. Bissilylenes can be categorized as compounds with two silylenes in a single molecule. In this mini review, recent work on the use of bissilylene ligand to investigate structural and chemical properties of their transition metal complexes and their catalytic applications is highlighted. Their utility as strong σ-donor ligand is well documented, which paves the way for several striking compounds.

Original language	English
Title of host publication	Discovering the Future of Molecular Sciences
Publisher	Wiley Blackwell
Pages	243-273
Number of pages	31
Volume	9783527335442
ISBN (Electronic)	9783527673223
ISBN (Print)	9783527335442
DOIs	https://doi.org/10.1002/9783527673223.ch10
State	Published - 11 Aug 2014
Externally published	Yes

Keywords

Bissilylene
Catalysis
Silicon
Silylene
Transition metals

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10.1002/9783527673223.ch10

Cite this

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KW - Catalysis

KW - Silicon

KW - Silylene

KW - Transition metals

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BT - Discovering the Future of Molecular Sciences

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ER -

The Next Generation of Silylene Ligands for Better Catalysts

Abstract

Keywords

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