The Molecular Structure of Tris(dimethylstibino)amine

Alexander Jockisch; Hubert Schmidbaur

doi:10.1515/znb-1998-1125

The Molecular Structure of Tris(dimethylstibino)amine

Alexander Jockisch
, Hubert Schmidbaur

Department of Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Tris(dimethylstibino)amine N(SbMe₂)₃ is formed during reactions of sodium dimethylstibide with haloalkanes in liquid ammonia. It forms colourless monoclinic crystals, a = 12.108(1), b = 6.663(1), c = 16.891(2) Å, β = 101.12(1)°. P2₁/c, Z = 4, at -78 °C. The lattice contains independent molecules with a planar NSb₃ core (sum of the angles at nitrogen 359.9°) and approximate C_3h symmetry.

Original language	English
Pages (from-to)	1386-1387
Number of pages	2
Journal	Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume	53
Issue number	11
DOIs	https://doi.org/10.1515/znb-1998-1125
State	Published - Nov 1998

Keywords

Aminostibine
Nitrogen Configuration
Planarity of Nitrogen
Tris(stibino)amine

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abstract = "Tris(dimethylstibino)amine N(SbMe2)3 is formed during reactions of sodium dimethylstibide with haloalkanes in liquid ammonia. It forms colourless monoclinic crystals, a = 12.108(1), b = 6.663(1), c = 16.891(2) {\AA}, β = 101.12(1)°. P21/c, Z = 4, at -78 °C. The lattice contains independent molecules with a planar NSb3 core (sum of the angles at nitrogen 359.9°) and approximate C3h symmetry.",

keywords = "Aminostibine, Nitrogen Configuration, Planarity of Nitrogen, Tris(stibino)amine",

author = "Alexander Jockisch and Hubert Schmidbaur",

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AU - Schmidbaur, Hubert

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N2 - Tris(dimethylstibino)amine N(SbMe2)3 is formed during reactions of sodium dimethylstibide with haloalkanes in liquid ammonia. It forms colourless monoclinic crystals, a = 12.108(1), b = 6.663(1), c = 16.891(2) Å, β = 101.12(1)°. P21/c, Z = 4, at -78 °C. The lattice contains independent molecules with a planar NSb3 core (sum of the angles at nitrogen 359.9°) and approximate C3h symmetry.

AB - Tris(dimethylstibino)amine N(SbMe2)3 is formed during reactions of sodium dimethylstibide with haloalkanes in liquid ammonia. It forms colourless monoclinic crystals, a = 12.108(1), b = 6.663(1), c = 16.891(2) Å, β = 101.12(1)°. P21/c, Z = 4, at -78 °C. The lattice contains independent molecules with a planar NSb3 core (sum of the angles at nitrogen 359.9°) and approximate C3h symmetry.

KW - Aminostibine

KW - Nitrogen Configuration

KW - Planarity of Nitrogen

KW - Tris(stibino)amine

UR - https://www.scopus.com/pages/publications/0346459215

U2 - 10.1515/znb-1998-1125

DO - 10.1515/znb-1998-1125

M3 - Article

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SN - 0932-0776

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JO - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

JF - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

IS - 11

ER -

The Molecular Structure of Tris(dimethylstibino)amine

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Keywords

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