TY - JOUR
T1 - The Molecular Structure of Tris(dimethylstibino)amine
AU - Jockisch, Alexander
AU - Schmidbaur, Hubert
PY - 1998/11
Y1 - 1998/11
N2 - Tris(dimethylstibino)amine N(SbMe2)3 is formed during reactions of sodium dimethylstibide with haloalkanes in liquid ammonia. It forms colourless monoclinic crystals, a = 12.108(1), b = 6.663(1), c = 16.891(2) Å, β = 101.12(1)°. P21/c, Z = 4, at -78 °C. The lattice contains independent molecules with a planar NSb3 core (sum of the angles at nitrogen 359.9°) and approximate C3h symmetry.
AB - Tris(dimethylstibino)amine N(SbMe2)3 is formed during reactions of sodium dimethylstibide with haloalkanes in liquid ammonia. It forms colourless monoclinic crystals, a = 12.108(1), b = 6.663(1), c = 16.891(2) Å, β = 101.12(1)°. P21/c, Z = 4, at -78 °C. The lattice contains independent molecules with a planar NSb3 core (sum of the angles at nitrogen 359.9°) and approximate C3h symmetry.
KW - Aminostibine
KW - Nitrogen Configuration
KW - Planarity of Nitrogen
KW - Tris(stibino)amine
UR - http://www.scopus.com/inward/record.url?scp=0346459215&partnerID=8YFLogxK
U2 - 10.1515/znb-1998-1125
DO - 10.1515/znb-1998-1125
M3 - Article
AN - SCOPUS:0346459215
SN - 0932-0776
VL - 53
SP - 1386
EP - 1387
JO - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
JF - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
IS - 11
ER -