The Molecular Structure of Tris(dimethylstibino)amine

Alexander Jockisch, Hubert Schmidbaur

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

Tris(dimethylstibino)amine N(SbMe2)3 is formed during reactions of sodium dimethylstibide with haloalkanes in liquid ammonia. It forms colourless monoclinic crystals, a = 12.108(1), b = 6.663(1), c = 16.891(2) Å, β = 101.12(1)°. P21/c, Z = 4, at -78 °C. The lattice contains independent molecules with a planar NSb3 core (sum of the angles at nitrogen 359.9°) and approximate C3h symmetry.

Original languageEnglish
Pages (from-to)1386-1387
Number of pages2
JournalZeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume53
Issue number11
DOIs
StatePublished - Nov 1998
Externally publishedYes

Keywords

  • Aminostibine
  • Nitrogen Configuration
  • Planarity of Nitrogen
  • Tris(stibino)amine

Fingerprint

Dive into the research topics of 'The Molecular Structure of Tris(dimethylstibino)amine'. Together they form a unique fingerprint.

Cite this