The Laser Induced Fluorescence Spectrum of the sym-Trichlorotrifluorobenzene Radical Cation in the Gas Phase

T. J. Sears; Terry A. Miller; V. E. Bondybey

doi:10.1021/ja00535a002

The Laser Induced Fluorescence Spectrum of the sym-Trichlorotrifluorobenzene Radical Cation in the Gas Phase

T. J. Sears, Terry A. Miller, V. E. Bondybey

Alcatel-Lucent

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11 Scopus citations

Abstract

The laser induced fluorescence excitation spectrum of the trichlorotrifluorobenzene radical cation in the gas phase has been obtained. The spectrum is analyzed in terms of excitation to both a1’ and e’ species vibrational modes in the B 2A2” state, consistent with the presence of Jahn-Teller perturbations in the ground X 2E” state of the ion. Comparison of the spectrum with that previously obtained in the Ne matrix environment suggests that there is little matrix perturbation.

Original language	English
Pages (from-to)	4864-4866
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	102
Issue number	15
DOIs	https://doi.org/10.1021/ja00535a002
State	Published - Jul 1980
Externally published	Yes

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title = "The Laser Induced Fluorescence Spectrum of the sym-Trichlorotrifluorobenzene Radical Cation in the Gas Phase",

abstract = "The laser induced fluorescence excitation spectrum of the trichlorotrifluorobenzene radical cation in the gas phase has been obtained. The spectrum is analyzed in terms of excitation to both a1{\textquoteright} and e{\textquoteright} species vibrational modes in the B 2A2” state, consistent with the presence of Jahn-Teller perturbations in the ground X 2E” state of the ion. Comparison of the spectrum with that previously obtained in the Ne matrix environment suggests that there is little matrix perturbation.",

author = "Sears, \{T. J.\} and Miller, \{Terry A.\} and Bondybey, \{V. E.\}",

year = "1980",

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language = "English",

volume = "102",

pages = "4864--4866",

journal = "Journal of the American Chemical Society",

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T1 - The Laser Induced Fluorescence Spectrum of the sym-Trichlorotrifluorobenzene Radical Cation in the Gas Phase

AU - Sears, T. J.

AU - Miller, Terry A.

AU - Bondybey, V. E.

PY - 1980/7

Y1 - 1980/7

N2 - The laser induced fluorescence excitation spectrum of the trichlorotrifluorobenzene radical cation in the gas phase has been obtained. The spectrum is analyzed in terms of excitation to both a1’ and e’ species vibrational modes in the B 2A2” state, consistent with the presence of Jahn-Teller perturbations in the ground X 2E” state of the ion. Comparison of the spectrum with that previously obtained in the Ne matrix environment suggests that there is little matrix perturbation.

AB - The laser induced fluorescence excitation spectrum of the trichlorotrifluorobenzene radical cation in the gas phase has been obtained. The spectrum is analyzed in terms of excitation to both a1’ and e’ species vibrational modes in the B 2A2” state, consistent with the presence of Jahn-Teller perturbations in the ground X 2E” state of the ion. Comparison of the spectrum with that previously obtained in the Ne matrix environment suggests that there is little matrix perturbation.

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DO - 10.1021/ja00535a002

M3 - Article

AN - SCOPUS:19944391781

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JF - Journal of the American Chemical Society

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ER -

The Laser Induced Fluorescence Spectrum of the sym-Trichlorotrifluorobenzene Radical Cation in the Gas Phase

Abstract

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