The identification of some novel four-membered ring cyclic triphosphenium ions in solution

Keith B. Dillon; Philippa K. Monks; Richard J. Olivey; Hans H. Karsch

doi:10.1002/hc.20043

The identification of some novel four-membered ring cyclic triphosphenium ions in solution

Keith B. Dillon
, Philippa K. Monks
, Richard J. Olivey
, Hans H. Karsch

Natural Sciences

University of Durham

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

The first four-membered ring cyclic triphosphenium ions with carbon substituents (methyl or cyclohexyl) on the outer phosphorus atoms have been identified in solution by ³¹P NMR spectroscopy. The cyclohexyl derivative in the presence of [SnCl₆]^2- as counterion was stable enough for methylation by methyl triflate to be carried out.

Original language	English
Pages (from-to)	464-467
Number of pages	4
Journal	Heteroatom Chemistry
Volume	15
Issue number	6
DOIs	https://doi.org/10.1002/hc.20043
State	Published - 2004

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10.1002/hc.20043

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@article{91bc7187da184798aa0959598980f52a,

title = "The identification of some novel four-membered ring cyclic triphosphenium ions in solution",

abstract = "The first four-membered ring cyclic triphosphenium ions with carbon substituents (methyl or cyclohexyl) on the outer phosphorus atoms have been identified in solution by 31P NMR spectroscopy. The cyclohexyl derivative in the presence of [SnCl6]2- as counterion was stable enough for methylation by methyl triflate to be carried out.",

author = "Dillon, \{Keith B.\} and Monks, \{Philippa K.\} and Olivey, \{Richard J.\} and Karsch, \{Hans H.\}",

year = "2004",

doi = "10.1002/hc.20043",

language = "English",

volume = "15",

pages = "464--467",

journal = "Heteroatom Chemistry",

issn = "1042-7163",

publisher = "John Wiley and Sons Inc",

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T1 - The identification of some novel four-membered ring cyclic triphosphenium ions in solution

AU - Dillon, Keith B.

AU - Monks, Philippa K.

AU - Olivey, Richard J.

AU - Karsch, Hans H.

PY - 2004

Y1 - 2004

N2 - The first four-membered ring cyclic triphosphenium ions with carbon substituents (methyl or cyclohexyl) on the outer phosphorus atoms have been identified in solution by 31P NMR spectroscopy. The cyclohexyl derivative in the presence of [SnCl6]2- as counterion was stable enough for methylation by methyl triflate to be carried out.

AB - The first four-membered ring cyclic triphosphenium ions with carbon substituents (methyl or cyclohexyl) on the outer phosphorus atoms have been identified in solution by 31P NMR spectroscopy. The cyclohexyl derivative in the presence of [SnCl6]2- as counterion was stable enough for methylation by methyl triflate to be carried out.

UR - https://www.scopus.com/pages/publications/6344282390

U2 - 10.1002/hc.20043

DO - 10.1002/hc.20043

M3 - Article

AN - SCOPUS:6344282390

SN - 1042-7163

VL - 15

SP - 464

EP - 467

JO - Heteroatom Chemistry

JF - Heteroatom Chemistry

IS - 6

ER -

The identification of some novel four-membered ring cyclic triphosphenium ions in solution

Abstract

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