Abstract
Nickel (111) and the interface of hexagonal boron nitride on Ni(111) serve as model systems for an itinerant ferromagnet that is truncated with vacuum or a single layer insulator. These systems are investigated with angle-scanned He I and He II photoemission. Upon formation of the h-BN/Ni(111) interface the work function drops by 1.8 eV and the minority Ni Λ3 d-band shifts by 0.13 eV to higher binding energy. This indicates that the Ni magnetic moment decreases in the interface. Spin-polarized band structure calculations from bulk nickel identify the observed minority and majority bands. The experimental Fermi surface maps show that h-BN distorts a minority d-band in a way which is consistent with the decreasing magnetic moment. It can be seen that h-BN affects the scattering of the electrons. Effects in the photoemission final and initial state are recognized.
Original language | English |
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Pages (from-to) | 1243-1250 |
Number of pages | 8 |
Journal | Surface Review and Letters |
Volume | 9 |
Issue number | 2 |
DOIs | |
State | Published - Apr 2002 |
Externally published | Yes |