The Complex Ions [C5H5M(CO)3]⊖ (MMo, W) as 6e‐Ligands: Synthesis and Molecular Structure of [(η4‐C4Me4)‐Co(μ‐CO)3M(η5)] (MMo, W)

Peter Härter; Heike Pfisterer; Manfred L. Ziegler

doi:10.1002/anie.198608391

The Complex Ions [C₅H₅M(CO)₃]^⊖ (MMo, W) as 6e‐Ligands: Synthesis and Molecular Structure of [(η⁴‐C₄Me₄)‐Co(μ‐CO)₃M(η⁵)] (MMo, W)

Peter Härter, Heike Pfisterer, Manfred L. Ziegler

Natural Sciences

Heidelberg University

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

A model example for the isolobal analogy between the 6e‐donor [(C₅H₅)M(CO)₃]^⊖ and C₅H 5⊖ (see previous communication) is the title compund 2. It is formed upon thermal elimination of CO from 1. The symmetric coordination of the (C₅H₅)W(CO)₃ fragment has been confirmed by X‐ray structure analysis. (Figure Presented.)

Original language	English
Pages (from-to)	839-840
Number of pages	2
Journal	Angewandte Chemie International Edition in English
Volume	25
Issue number	9
DOIs	https://doi.org/10.1002/anie.198608391
State	Published - Sep 1986

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title = "The Complex Ions [C5H5M(CO)3]⊖ (MMo, W) as 6e‐Ligands: Synthesis and Molecular Structure of [(η4‐C4Me4)‐Co(μ‐CO)3M(η5)] (MMo, W)",

abstract = "A model example for the isolobal analogy between the 6e‐donor [(C5H5)M(CO)3]⊖ and C5H 5⊖ (see previous communication) is the title compund 2. It is formed upon thermal elimination of CO from 1. The symmetric coordination of the (C5H5)W(CO)3 fragment has been confirmed by X‐ray structure analysis. (Figure Presented.)",

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year = "1986",

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AU - Härter, Peter

AU - Pfisterer, Heike

AU - Ziegler, Manfred L.

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N2 - A model example for the isolobal analogy between the 6e‐donor [(C5H5)M(CO)3]⊖ and C5H 5⊖ (see previous communication) is the title compund 2. It is formed upon thermal elimination of CO from 1. The symmetric coordination of the (C5H5)W(CO)3 fragment has been confirmed by X‐ray structure analysis. (Figure Presented.)

AB - A model example for the isolobal analogy between the 6e‐donor [(C5H5)M(CO)3]⊖ and C5H 5⊖ (see previous communication) is the title compund 2. It is formed upon thermal elimination of CO from 1. The symmetric coordination of the (C5H5)W(CO)3 fragment has been confirmed by X‐ray structure analysis. (Figure Presented.)

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The Complex Ions [C₅H₅M(CO)₃]^⊖ (MMo, W) as 6e‐Ligands: Synthesis and Molecular Structure of [(η⁴‐C₄Me₄)‐Co(μ‐CO)₃M(η⁵)] (MMo, W)

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