The Boratobis(dimethylphosphiniomethylide) Anion, a Novel Ligand System for Organometallic Compounds

Hubert Schmidbaur; Gerhard Müller; Ulrich Schubert; Olli Orama

doi:10.1002/anie.197801261

The Boratobis(dimethylphosphiniomethylide) Anion, a Novel Ligand System for Organometallic Compounds

Hubert Schmidbaur
, Gerhard Müller
, Ulrich Schubert
, Olli Orama

Department of Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

Stable complexes of the new anion 1 have now been synthesized and characterized. In 3, MZn, Cd, Ni, all the Me₂PCH₂ groups are equivalent. X‐Ray structure analysis shows the six‐membered rings of the nickel compound to have a chair conformation. (Figure Presented.)

Original language	English
Pages (from-to)	126-127
Number of pages	2
Journal	Angewandte Chemie International Edition in English
Volume	17
Issue number	2
DOIs	https://doi.org/10.1002/anie.197801261
State	Published - Feb 1978

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@article{33b6074be73642aebe323a42d97ee8d4,

title = "The Boratobis(dimethylphosphiniomethylide) Anion, a Novel Ligand System for Organometallic Compounds",

abstract = "Stable complexes of the new anion 1 have now been synthesized and characterized. In 3, MZn, Cd, Ni, all the Me2PCH2 groups are equivalent. X‐Ray structure analysis shows the six‐membered rings of the nickel compound to have a chair conformation. (Figure Presented.)",

author = "Hubert Schmidbaur and Gerhard M{\"u}ller and Ulrich Schubert and Olli Orama",

year = "1978",

month = feb,

doi = "10.1002/anie.197801261",

language = "English",

volume = "17",

pages = "126--127",

journal = "Angewandte Chemie International Edition in English",

issn = "0570-0833",

publisher = "John Wiley and Sons Ltd",

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T1 - The Boratobis(dimethylphosphiniomethylide) Anion, a Novel Ligand System for Organometallic Compounds

AU - Schmidbaur, Hubert

AU - Müller, Gerhard

AU - Schubert, Ulrich

AU - Orama, Olli

PY - 1978/2

Y1 - 1978/2

N2 - Stable complexes of the new anion 1 have now been synthesized and characterized. In 3, MZn, Cd, Ni, all the Me2PCH2 groups are equivalent. X‐Ray structure analysis shows the six‐membered rings of the nickel compound to have a chair conformation. (Figure Presented.)

AB - Stable complexes of the new anion 1 have now been synthesized and characterized. In 3, MZn, Cd, Ni, all the Me2PCH2 groups are equivalent. X‐Ray structure analysis shows the six‐membered rings of the nickel compound to have a chair conformation. (Figure Presented.)

UR - https://www.scopus.com/pages/publications/84985520829

U2 - 10.1002/anie.197801261

DO - 10.1002/anie.197801261

M3 - Article

AN - SCOPUS:84985520829

SN - 0570-0833

VL - 17

SP - 126

EP - 127

JO - Angewandte Chemie International Edition in English

JF - Angewandte Chemie International Edition in English

IS - 2

ER -

The Boratobis(dimethylphosphiniomethylide) Anion, a Novel Ligand System for Organometallic Compounds

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