The Auration of Dimethylsulfide

Alexander Sladek; Hubert Schmidbaur

doi:10.1515/znb-1996-0822

The Auration of Dimethylsulfide

Alexander Sladek
, Hubert Schmidbaur

Department of Chemistry

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Dimethylsulfide reacts with (triphenylphosphine)gold(I) trifluoromethanesulfonate to give quantitative yields of the mixed ligand complex [(Ph₃P)Au(SMe₂)]⁺O₃SCF ₃^- (1). The structure of compound 1 has been determined by an X-ray crystal structure analysis. The lattice contains independent anions and (monomeric) cations, which have a linear P-Au-S axis. Attempts to produce a binuclear, dicationic complex through addition of a second equivalent of [(Ph₃P)Au]⁺ failed and lead to decomposition products including [(Ph₃P)₂Au]⁺O₃SCF₃ ^-.

Original language	English
Pages (from-to)	1207-1209
Number of pages	3
Journal	Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume	51
Issue number	8
DOIs	https://doi.org/10.1515/znb-1996-0822
State	Published - Aug 1996

Keywords

Gold(I) Complex
Mixed Ligand Complex
Thioether Complex

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title = "The Auration of Dimethylsulfide",

abstract = "Dimethylsulfide reacts with (triphenylphosphine)gold(I) trifluoromethanesulfonate to give quantitative yields of the mixed ligand complex [(Ph3P)Au(SMe2)]+O3SCF 3- (1). The structure of compound 1 has been determined by an X-ray crystal structure analysis. The lattice contains independent anions and (monomeric) cations, which have a linear P-Au-S axis. Attempts to produce a binuclear, dicationic complex through addition of a second equivalent of [(Ph3P)Au]+ failed and lead to decomposition products including [(Ph3P)2Au]+O3SCF3 -.",

keywords = "Gold(I) Complex, Mixed Ligand Complex, Thioether Complex",

author = "Alexander Sladek and Hubert Schmidbaur",

year = "1996",

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doi = "10.1515/znb-1996-0822",

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pages = "1207--1209",

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T1 - The Auration of Dimethylsulfide

AU - Sladek, Alexander

AU - Schmidbaur, Hubert

PY - 1996/8

Y1 - 1996/8

N2 - Dimethylsulfide reacts with (triphenylphosphine)gold(I) trifluoromethanesulfonate to give quantitative yields of the mixed ligand complex [(Ph3P)Au(SMe2)]+O3SCF 3- (1). The structure of compound 1 has been determined by an X-ray crystal structure analysis. The lattice contains independent anions and (monomeric) cations, which have a linear P-Au-S axis. Attempts to produce a binuclear, dicationic complex through addition of a second equivalent of [(Ph3P)Au]+ failed and lead to decomposition products including [(Ph3P)2Au]+O3SCF3 -.

AB - Dimethylsulfide reacts with (triphenylphosphine)gold(I) trifluoromethanesulfonate to give quantitative yields of the mixed ligand complex [(Ph3P)Au(SMe2)]+O3SCF 3- (1). The structure of compound 1 has been determined by an X-ray crystal structure analysis. The lattice contains independent anions and (monomeric) cations, which have a linear P-Au-S axis. Attempts to produce a binuclear, dicationic complex through addition of a second equivalent of [(Ph3P)Au]+ failed and lead to decomposition products including [(Ph3P)2Au]+O3SCF3 -.

KW - Gold(I) Complex

KW - Mixed Ligand Complex

KW - Thioether Complex

UR - https://www.scopus.com/pages/publications/0347876972

U2 - 10.1515/znb-1996-0822

DO - 10.1515/znb-1996-0822

M3 - Article

AN - SCOPUS:0347876972

SN - 0932-0776

VL - 51

SP - 1207

EP - 1209

JO - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

JF - Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences

IS - 8

ER -

The Auration of Dimethylsulfide

Abstract

Keywords

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