The adsorption of CO on Ni W(110): a joint experimental and theoretical study

Peter Maciejewski; Wilfried Wurth; Sibylle Köstlmeier; Gianfranco Pacchioni; Notker Rösch

doi:10.1016/0039-6028(95)00398-3

The adsorption of CO on Ni W(110): a joint experimental and theoretical study

Peter Maciejewski, Wilfried Wurth, Sibylle Köstlmeier, Gianfranco Pacchioni, Notker Rösch

Associate Professorship of Theoretical Chemistry (2008 — 2024)

Technical University of Munich

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

We present a detailed experimental study of the geometric, electronic and adsorptive properties of ultrathin Ni films on a W(110) surface. In parallel we have performed calculations on clusters representing the bimetallic system in order to improve the understanding of the relationship between the chemical properties of ultrathin metal films and their geometric as well as electronic structure. Our results indicate that the modification of the electronic structure induced by the intermetallic bond is the most important factor in determining the unique properties of metallic overlayers.

Original language	English
Pages (from-to)	156-172
Number of pages	17
Journal	Surface Science
Volume	330
Issue number	2
DOIs	https://doi.org/10.1016/0039-6028(95)00398-3
State	Published - 10 Jun 1995

Keywords

Auger electron spectroscopy
Carbon monoxide
Chemisorption
Density functional calculations
Metallic films
Nickel
Photoelectron spectroscopy
Single crystal surfaces
Tungsten

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10.1016/0039-6028(95)00398-3

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title = "The adsorption of CO on Ni W(110): a joint experimental and theoretical study",

abstract = "We present a detailed experimental study of the geometric, electronic and adsorptive properties of ultrathin Ni films on a W(110) surface. In parallel we have performed calculations on clusters representing the bimetallic system in order to improve the understanding of the relationship between the chemical properties of ultrathin metal films and their geometric as well as electronic structure. Our results indicate that the modification of the electronic structure induced by the intermetallic bond is the most important factor in determining the unique properties of metallic overlayers.",

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author = "Peter Maciejewski and Wilfried Wurth and Sibylle K{\"o}stlmeier and Gianfranco Pacchioni and Notker R{\"o}sch",

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T1 - The adsorption of CO on Ni W(110)

T2 - a joint experimental and theoretical study

AU - Maciejewski, Peter

AU - Wurth, Wilfried

AU - Köstlmeier, Sibylle

AU - Pacchioni, Gianfranco

AU - Rösch, Notker

PY - 1995/6/10

Y1 - 1995/6/10

N2 - We present a detailed experimental study of the geometric, electronic and adsorptive properties of ultrathin Ni films on a W(110) surface. In parallel we have performed calculations on clusters representing the bimetallic system in order to improve the understanding of the relationship between the chemical properties of ultrathin metal films and their geometric as well as electronic structure. Our results indicate that the modification of the electronic structure induced by the intermetallic bond is the most important factor in determining the unique properties of metallic overlayers.

AB - We present a detailed experimental study of the geometric, electronic and adsorptive properties of ultrathin Ni films on a W(110) surface. In parallel we have performed calculations on clusters representing the bimetallic system in order to improve the understanding of the relationship between the chemical properties of ultrathin metal films and their geometric as well as electronic structure. Our results indicate that the modification of the electronic structure induced by the intermetallic bond is the most important factor in determining the unique properties of metallic overlayers.

KW - Auger electron spectroscopy

KW - Carbon monoxide

KW - Chemisorption

KW - Density functional calculations

KW - Metallic films

KW - Nickel

KW - Photoelectron spectroscopy

KW - Single crystal surfaces

KW - Tungsten

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DO - 10.1016/0039-6028(95)00398-3

M3 - Article

AN - SCOPUS:0029323708

SN - 0039-6028

VL - 330

SP - 156

EP - 172

JO - Surface Science

JF - Surface Science

IS - 2

ER -

The adsorption of CO on Ni W(110): a joint experimental and theoretical study

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Keywords

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