Abstract
Treatment of tricyclohexylphosphine(trimethylsilyl)borane with tris[(triphenylphosphine)gold(I)]oxonium tetrafluoro-borate [in tetrahydrofuran (thf) at -78°C] affords moderate yields of the title compound [(Cy 3P)B(AuPPh3)4]+ BF4 -, the cation of which features pentacoordinate boron atoms in the centre of a (pseudo) square pyramid with the Cy 3P ligand in the apical position (Cy = cyclohexyl).
Original language | English |
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Pages (from-to) | 1005-1006 |
Number of pages | 2 |
Journal | Journal of the Chemical Society, Chemical Communications |
Issue number | 12 |
DOIs | |
State | Published - 1993 |